Uncatalysed reactions in water: Part 2. Preparation of 3-carboxycoumarins

被引：89

作者：

Maggi, R ^{[1
]}

Bigi, F ^{[1
]}

Carloni, S ^{[1
]}

Mazzacani, A ^{[1
]}

Sartori, G ^{[1
]}

机构：

[1] Univ Parma, Dipartimento Chim Organ & Ind, I-43100 Parma, Italy

来源：

GREEN CHEMISTRY | 2001年 / 3卷 / 04期

关键词：

D O I：

10.1039/b101822c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A simple, efficient and environmentally friendly procedure has been developed for the reaction of Meldrum's acid with salicylaldehydes. 3-Carboxycoumarins 5 were synthesised in high yields (78-96%) and excellent selectivities (95-98%) by carrying out the reaction in water at reflux for 10 h, avoiding the addition of any catalyst.

引用

页码：173 / 174

页数：2

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