Structure of extremely nanosized and confined In-O species in ordered porous materials -: art. no. 108304

被引：11
作者：
Ramallo-López, JM
Rentería, M
Miró, EE
Requejo, FG
Traverse, A
机构：
[1] Natl Univ La Plata, Dept Fis, FCE, RA-1900 La Plata, Argentina
[2] Univ Paris 11, LURE, F-91898 Orsay, France
[3] Consejo Nacl Invest Cient & Tecn, INCAPE, FIQ, UNL, RA-3000 Santa Fe, Argentina
[4] Univ Calif Berkeley, Lawrence Berkeley Lab, Berkeley, CA 94720 USA
来源：
PHYSICAL REVIEW LETTERS | 2003年 / 91卷 / 10期
关键词：
D O I：
10.1103/PhysRevLett.91.108304
中图分类号：
O4 [物理学];
学科分类号：
0702 ;
摘要：
Perturbed-angular correlation, x-ray absorption, and small-angle x-ray scattering spectroscopies were suitably combined to elucidate the local structure of highly diluted and dispersed InOx species confined in the porous of the ZSM5 zeolite. This novel approach allow us to determined the structure of extremely nanosized In-O species exchanged inside the 10-atom-ring channel of the zeolite, and to quantify the amount of In2O3 crystallites deposited onto the external zeolite surface.
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