Manganese(III) bis(2-hydroxyanil)acetylacetonato complex as effective catalyst for acylation of alcohols, amines and phenols with acetic anhydride

被引：30

作者：

Salavati-Niasari, M

Hydarzadeh, S

Amiri, A

Salavati, S

机构：

[1] Univ Kashan, Dept Chem, Kashan 87317, Iran

[2] Payam Noor Univ Aran, Kashan, Iran

来源：

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 2005年 / 231卷 / 1-2期

关键词：

acylation; Mn(III); Schiff-base; alcohol acetic anhydride; phenol; amine;

D O I：

10.1016/j.molcata.2005.01.013

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Acylation of alcohols, amines and phenols with acetic anhydride in an efficient manner using [bis(2-hydroxyanil)acetylacetonato]manganese(III)chloride, [Mn(haacac)Cl], as a catalyst. Using this method acylation of a primary NH2 group in the presence of secondary NH and primary OH have been achieved with high selectivity. (c) 2005 Elsevier B.V. All rights reserved.

引用

页码：191 / 195

页数：5

共 47 条

[1] The catalytic acylation of alcohols with acetic acid by using Lewis acid character pillared clays
Akçay, M
[J]. APPLIED CATALYSIS A-GENERAL, 2004, 269 (1-2) : 157 - 160
[2] [Anonymous], ORGANIC SYNTHESES CO
[3] Baker RH., 1955, ORG SYNTH, P141
[4] Zeolite HSZ-360 as a new reusable catalyst for the direct acetylation of alcohols and phenols under solventless conditions
Ballini, R
Bosica, G
Carloni, S
Ciaralli, L
Maggi, R
Sartori, G
[J]. TETRAHEDRON LETTERS, 1998, 39 (33) : 6049 - 6052
[5] Indium(III) chloride as a new, highly efficient, and versatile catalyst for acylation of phenols, thiols, alcohols, and amines
Chakraborti, AK
Gulhane, R
[J]. TETRAHEDRON LETTERS, 2003, 44 (35) : 6749 - 6753
[6] Fluoroboric acid adsorbed on silica gel as a new and efficient catalyst for acylation of phenols, thiols, alcohols, and amines
Chakraborti, AK
Gulhane, R
[J]. TETRAHEDRON LETTERS, 2003, 44 (17) : 3521 - 3525
[7] Acylation of alcohols with acetic anhydride catalyzed by TaCl5:: Some implications in kinetic resolution
Chandrasekhar, S
Ramachander, T
Takhi, M
[J]. TETRAHEDRON LETTERS, 1998, 39 (20) : 3263 - 3266
[8] Chauhan KK, 1999, SYNLETT, P1743
[9] Cope A.C., 1963, ORG SYNTH, V4, P304
[10] Ruthenium(III) chloride catalyzed acylation of alcohols, phenols, thiols, and amines
De, SK
[J]. TETRAHEDRON LETTERS, 2004, 45 (14) : 2919 - 2922

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