Highly Active Palladium Catalysts with Bisacetylacetonate Ligands for Suzuki-Miyaura Cross-coupling Reactions in Mild Conditions

被引：1

作者：

Liu, Wanyun ^{[1
]}

Xiong, Dayan ^{[1
]}

Huo, Ping ^{[1
]}

Mei, Guangquan ^{[1
,2
]}

机构：

[1] Yichun Univ, Jiangxi Univ Appl Chem & Chem Biol, Key Lab, Yichun 336000, Peoples R China

[2] Nanjing Univ, State Key Lab Coordinat Chem, Nanjing 210093, Jiangsu, Peoples R China

来源：

CHEMISTRY LETTERS | 2017年 / 46卷 / 10期

基金：

中国国家自然科学基金;

关键词：

Bisacetylacetonate ligand; Palladium catalyst; Suzuki-Miyaura cross-coupling reaction; COMPLEXES;

D O I：

10.1246/cl.170705

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In the presence of Pd(OAc)(2), three bisacetylacetonate ligands were demonstrated to form a highly efficient catalyst for the Suzuki-Miyaura cross-coupling reactions. The most active bisacetylacetonate ligand with anthracene groups on the backbone showed a wide substrate scope in excellent yields using very low catalyst concentration of 0.01 mol% in ethanol/aqueous media under ambient atmosphere.

引用

页码：1550 / 1552

页数：3

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