(D-π-)2D-π-A-Type Organic Dyes for Efficient Dye-Sensitized Solar Cells

被引：17

作者：

Kaewpuang, Terdkait ^{[1
]}

Prachumrak, Narid ^{[2
]}

Namuangruk, Supawadee ^{[3
]}

Jungsuttiwong, Siriporn ^{[4
]}

Sudyoadsuk, Taweesak ^{[2
]}

Pattanasattayavong, Pichaya ^{[2
]}

Promarak, Vinich ^{[2
]}

机构：

[1] Suranaree Univ Technol, Sch Chem, Inst Sci, Nakhon Ratchasima 30000, Thailand

[2] Vidyasirimedhi Inst Sci & Technol, Sch Mol Sci & Engn, Dept Mat Sci & Engn, Wangchan 21210, Rayong, Thailand

[3] Natl Sci & Technol Dev Agcy, NANOTEC, 111 Phahonyothin Rd, Khlong Luang 12120, Pathum Thani, Thailand

[4] Ubon Ratchathani Univ, Fac Sci, Dept Chem, Ubon Ratchathani 34190, Thailand

来源：

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY | 2016年 / 2016卷 / 14期

关键词：

Dyes/Pigments; Donor-acceptor systems; Density functional calculations; Dye-sensitized solar cells; D-PI-A; MOLECULAR DESIGN; AUXILIARY DONOR; SOLID-STATE; PERFORMANCE; LIGHT; PHTHALOCYANINE; RECOMBINATION; ELECTROLYTE; ABSORPTION;

D O I：

10.1002/ejoc.201600190

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

New (D-pi-)(2)D-pi-A-type dyes (CFTTnA, n = 2, 3) with a triarylamine as electron donor, a cyanoacrylic acid as both electron acceptor and anchoring group, and two pi-conjugated 2-[7-(3,6-di-tert-butylcarbazol-9-yl)-9,9-dihexylfluoren-2-yl]thiophenes as N-aryl substituents on the amine donor as co-donors have been synthesized and characterized. Compared with a traditional D-pi-A-type dye, these dyes exhibit broader absorption spectra and higher molar extinction coefficients as well as significantly enhanced photovoltaic performances. A power conversion efficiency of 6.64 % was achieved for a dye-sensitized solar cell (DSSC) based on CFTT3A. Theoretical calculations and electrochemical impedance spectroscopic investigations revealed the mechanism of the enhanced dye properties and cell performances.

引用

页码：2528 / 2538

页数：11

共 70 条

[1] A new route towards fluorescent organic nanoparticles with red-shifted emission and increased colloidal stability [J].

Amro, Kassem ;

Daniel, Jonathan ;

Clermont, Guillaume ;

Bsaibess, Talia ;

Pucheault, Mathieu ;

Genin, Emilie ;

Vaultier, Michel ;

Blanchard-Desce, Mireille .

TETRAHEDRON, 2014, 70 (10) :1903-1909

[2] Ruthenium complex-cored dendrimers: Shedding light on efficiency trade-offs in dye-sensitised solar cells [J].

An, Byeong-Kwan ;

Mulherin, Rhiannon ;

Langley, Benjamin ;

Burn, Paul ;

Meredith, Paul .

ORGANIC ELECTRONICS, 2009, 10 (07) :1356-1363

[3] Fluorene-Based Sensitizers with a Phenothiazine Donor: Effect of Mode of Donor Tethering on the Performance of Dye-Sensitized Solar Cells [J].

Baheti, Abhishek ;

Thomas, K. R. Justin ;

Li, Chun-Ting ;

Lee, Chuan-Pei ;

Ho, Kuo-Chuan .

ACS APPLIED MATERIALS & INTERFACES, 2015, 7 (04) :2249-2262

[4] Monoanchoring (D-D-π-A) and Dianchoring (D-D-(π-A)2) Organic Dyes Featuring Triarylamine Donors Composed of Fluorene and Carbazole [J].

Baheti, Abhishek ;

Thomas, K. R. Justin ;

Lin, Ling-Chuan ;

Lee, Kun-Mu .

ASIAN JOURNAL OF ORGANIC CHEMISTRY, 2014, 3 (08) :886-898

[5] 2,7-Diaminofluorene-Based Organic Dyes for Dye-Sensitized Solar Cells: Effect of Auxiliary Donor on Optical and Electrochemical Properties [J].

Baheti, Abhishek ;

Singh, Prachi ;

Lee, Chuan-Pei ;

Thomas, K. R. Justin ;

Ho, Kuo-Chuan .

JOURNAL OF ORGANIC CHEMISTRY, 2011, 76 (12) :4910-4920

[6] Dye-sensitized solar cell utilizing organic dyads containing triarylene conjugates [J].

Chang, Yuan Jay ;

Chow, Tahsin J. .

TETRAHEDRON, 2009, 65 (24) :4726-4734

[7] High Molar Extinction Coefficient Branchlike Organic Dyes Containing Di(p-tolyl)phenylamine Donor for Dye-Sensitized Solar Cells Applications [J].

Chen, Huajie ;

Huang, Hui ;

Huang, Xianwei ;

Clifrord, John N. ;

Forneli, Amparo ;

Palomares, Emilio ;

Zheng, Xiaoyan ;

Zheng, Liping ;

Wang, Xianyou ;

Shen, Ping ;

Zhao, Bin ;

Tan, Songting .

JOURNAL OF PHYSICAL CHEMISTRY C, 2010, 114 (07) :3280-3286

[8] Synthesis of Conjugated Polymers for Organic Solar Cell Applications [J].

Cheng, Yen-Ju ;

Yang, Sheng-Hsiung ;

Hsu, Chain-Shu .

CHEMICAL REVIEWS, 2009, 109 (11) :5868-5923

[9] Highly efficient and thermally stable organic sensitizers for solvent-free dye-sensitized solar cells [J].

Choi, Hyunbong ;

Baik, Chul ;

Kang, Sang Ook ;

Ko, Jaejung ;

Kang, Moon-Sung ;

Nazeeruddin, Md. K. ;

Graetzel, Michael .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (02) :327-330

[10] Influence of the Terminal Electron Donor in D-D-π-A Organic Dye-Sensitized Solar Cells: Dithieno[3,2-b:2′,3′-d]pyrrole versus Bis(amine) [J].

Dai, Panpan ;

Yang, Lin ;

Liang, Mao ;

Dong, Huanhuan ;

Wang, Peng ;

Zhang, Chunyao ;

Sun, Zhe ;

Xue, Song .

ACS APPLIED MATERIALS & INTERFACES, 2015, 7 (40) :22436-22447

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