Panchromatic engineering for dye-sensitized solar cells

被引:313
作者
Yum, Jun-Ho [1 ]
Baranoff, Etienne [1 ]
Wenger, Sophie [1 ]
Nazeeruddin, Md. K. [1 ]
Graetzel, Michael [1 ]
机构
[1] Ecole Polytech Fed Lausanne, Inst Chem Sci & Engn, Lab Photon & Interfaces, Stn 6, CH-1015 Lausanne, Switzerland
基金
瑞士国家科学基金会;
关键词
NANOCRYSTALLINE TIO2 FILMS; TITANIUM-DIOXIDE FILMS; CHARGE RECOMBINATION KINETICS; POWER-CONVERSION EFFICIENCY; OPEN-CIRCUIT VOLTAGE; ENERGY RELAY DYES; THIN ABSORBER ETA; QUANTUM DOTS; RUTHENIUM SENSITIZERS; ELECTRON INJECTION;
D O I
10.1039/c0ee00536c
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The dye-sensitized mesoscopic solar cell has been intensively investigated as a promising photovoltaic cell. Its ecological and economical fabrication processes make it attractive and credible alternative to conventional photovoltaic systems. In contrast to the latter design, the DSC approach separates tasks of light absorption and charge transport. The primary step of light absorption is performed by a sensitizer anchored to the surface of a wide band gap semiconductor. In order to reach a high conversion efficiency, the first requirement is that the sensitizer should absorb as much as possible of the incoming sunlight. Strategies for achieving panchromatic response in dye-sensitized mesoscopic solar cells are discussed.
引用
收藏
页码:842 / 857
页数:16
相关论文
共 140 条
  • [1] Semiconductor clusters, nanocrystals, and quantum dots
    Alivisatos, AP
    [J]. SCIENCE, 1996, 271 (5251) : 933 - 937
  • [2] Sensitization of nanocrystalline TiO2 with black absorbers based on Os and Ru polypyridine complexes
    Altobello, S
    Argazzi, R
    Caramori, S
    Contado, C
    Da Fré, S
    Rubino, P
    Choné, C
    Larramona, G
    Bignozzi, CA
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (44) : 15342 - 15343
  • [3] CHEMICAL MODIFICATION OF A TITANIUM(IV) OXIDE ELECTRODE TO GIVE STABLE DYE SENSITIZATION WITHOUT A SUPERSENSITIZER
    ANDERSON, S
    CONSTABLE, EC
    DAREEDWARDS, MP
    GOODENOUGH, JB
    HAMNETT, A
    SEDDON, KR
    WRIGHT, RD
    [J]. NATURE, 1979, 280 (5723) : 571 - 573
  • [4] [Anonymous], 2003, World in transition towards sustainable energy systems
  • [5] Photodriven heterogeneous charge transfer with transition-metal compounds anchored to TiO2 semiconductor surfaces
    Ardo, Shane
    Meyer, Gerald J.
    [J]. CHEMICAL SOCIETY REVIEWS, 2009, 38 (01) : 115 - 164
  • [6] The future of energy supply: Challenges and opportunities
    Armaroli, Nicola
    Balzani, Vincenzo
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2007, 46 (1-2) : 52 - 66
  • [7] Polycrystalline thin film solar cells: Present status and future potential
    Birkmire, RW
    Eser, E
    [J]. ANNUAL REVIEW OF MATERIALS SCIENCE, 1997, 27 : 625 - 653
  • [8] Analysis of tandem solar cell efficiencies under AM1.5G spectrum using a rapid flux calculation method
    Bremner, S. P.
    Levy, M. Y.
    Honsberg, C. B.
    [J]. PROGRESS IN PHOTOVOLTAICS, 2008, 16 (03): : 225 - 233
  • [10] Dye-Sensitized Solar Cells with a High Absorptivity Ruthenium Sensitizer Featuring a 2-(Hexylthio)thiophene Conjugated Bipyridine
    Cao, Yiming
    Bai, Yu
    Yu, Qingjiang
    Cheng, Yueming
    Liu, Shi
    Shi, Dong
    Gao, Feifei
    Wang, Peng
    [J]. JOURNAL OF PHYSICAL CHEMISTRY C, 2009, 113 (15) : 6290 - 6297