Low-temperature hydrothermal liquefaction of pomelo peel for production of 5-hydroxymethylfurfural-rich bio-oil using ionic liquid loaded ZSM-5

被引：17

作者：

Wei, Yingyuan ^{[1
]}

Fakudze, Sandile ^{[1
]}

Zhang, Yu ^{[1
]}

Song, Min ^{[2
]}

Xue, Tianjiao ^{[1
]}

Xie, Ruiyan ^{[1
]}

Chen, Jianqiang ^{[1
]}

机构：

[1] Nanjing Forestry Univ, Coll Biol & Environm, Lab Adv Environm & Energy Mat, Nanjing 210037, Peoples R China

[2] Southeast Univ, Sch Energy & Environm, Key Lab Energy Thermal Convers & Control, Minist Educ, Nanjing 210096, Peoples R China

来源：

BIORESOURCE TECHNOLOGY | 2022年 / 352卷

关键词：

Catalytic hydrothermal liquefaction; Pomelo peel; Ionic liquids; Zeolite; Bio-oil; 5-Hydroxymethylfurfural; CELLULOSE; ZEOLITE; BIOMASS; MICROALGAE; HTL; HYDROLYSIS; SEPARATION; CONVERSION; EFFICIENT; CATALYST;

D O I：

10.1016/j.biortech.2022.127050

中图分类号：

S2 [农业工程];

学科分类号：

0828 ;

摘要：

Ionic liquid loaded ZSM-5 with high stability and catalytic performance was used for hydrothermal liquefaction (HTL) of pomelo peel for the first time. Bio-oil obtained at 200 degrees C had the highest yield (29.21 wt%) and high heating value (21.41 MJ/kg), with main constituents of 5-hydroxymethylfurfural (5-HMF, 50.10%), 3-Pyridinol (19.8%) and pentanoic acid (5.35%). The higher 5-hydroxymethylfurfural yield obtained using ionic liquid loaded ZSM-5 was further compared to other studies (0-50%). In comparison to high-temperature HTL, catalytic HTL with ionic liquid loaded ZSM-5 led to lower activation energy requirements (31.93 kJ.mol(-1)) for the conversion of glucose into 5-HMF. Additionally, the catalysts showed excellent recyclability, with 19.68 wt% of bio-oil containing 59.6% of light oil obtained after 5 cycles. Hence, this study presents a novel approach for the catalytic conversion of lignocellulosic biomass into 5-HMF-rich bio-oil for energy and green chemistry applications.

引用

页数：9

共 49 条

[11] Co-hydrothermal liquefaction of wastewater-grown algae and crude glycerol: A novel strategy of bio-crude oil-aqueous separation and techno-economic analysis for bio-crude oil recovery and upgrading [J].

Cui, Zheng ;

Greene, Jonah M. ;

Cheng, Feng ;

Quinn, Jason C. ;

Jena, Umakanta ;

Brewer, Catherine E. .

ALGAL RESEARCH-BIOMASS BIOFUELS AND BIOPRODUCTS, 2020, 51

[12] Catalytic hydrothermal liquefaction of rice straw for production of monomers phenol over metal supported mesoporous catalyst [J].

Ding, Yong-Jie ;

Zhao, Chun-Xiang ;

Liu, Zeng-Chen .

BIORESOURCE TECHNOLOGY, 2019, 294

[13] Activated carbons for the hydrothermal upgrading of crude duckweed bio-oil [J].

Duan, Peigao ;

Zhang, Caicai ;

Wang, Feng ;

Fu, Jie ;

Lu, Xiuyang ;

Xu, Yuping ;

Shi, Xianlei .

CATALYSIS TODAY, 2016, 274 :73-81

[14] Catalytic hydrothermal liquefaction of lactuca scariola with a heterogeneous catalyst: The investigation of temperature, reaction time and synergistic effect of catalysts [J].

Durak, Halil ;

Genel, Salih .

BIORESOURCE TECHNOLOGY, 2020, 309

[15] Hydrothermal liquefaction of Glycyrrhiza glabra L. (Liquorice): Effects of catalyst on variety compounds and chromatographic characterization [J].

Durak, Halil .

ENERGY SOURCES PART A-RECOVERY UTILIZATION AND ENVIRONMENTAL EFFECTS, 2020, 42 (20) :2471-2484

[16] Catalytic upgrading of biomass-derived vapors to bio-fuels via modified HZSM-5 coupled with DBD: Effects of different titanium sources [J].

Fan, Yongsheng ;

Zhu, Mengfeng ;

Jin, Lizhu ;

Cui, Entian ;

Zhu, Lei ;

Cai, Yixi ;

Zhao, Weidong .

RENEWABLE ENERGY, 2020, 157 :100-115

[17] Catalytic hydrothermal liquefaction of lignin for production of aromatic hydrocarbon over metal supported mesoporous catalyst [J].

Feng, Li ;

Li, Xuhao ;

Wang, Zizeng ;

Liu, Bingzhi .

BIORESOURCE TECHNOLOGY, 2021, 323

[18] Studies on Structural Changes and Catalytic Activity of Y-zeolite Composites of 1,3-disulfoimidazolium trifluoroacetate Ionic Liquid (IL) for Three Component Synthesis of 3,4-dihydropyrimidinones [J].

Gogoi, Pinky ;

Dutta, Arup Kumar ;

Borah, Ruli .

CATALYSIS LETTERS, 2017, 147 (03) :674-685

[19] Immobilizing Polyether Imidazole Ionic Liquids on ZSM-5 Zeolite for the Catalytic Synthesis of Propylene Carbonate from Carbon Dioxide [J].

Guo, Liying ;

Jin, Xianchao ;

Wang, Xin ;

Yin, Longzhu ;

Wang, Yirong ;

Yang, Ying-Wei .

MOLECULES, 2018, 23 (10)

[20]

Hao B., GREEN CHEM, V23, P1562

← 1 2 3 4 5 →