Bis[1,3-bis(1H-benzimidazol-2-yl)benzene-κN3](succinato-κ2O,O′) zinc(II), a succinate-chelated monomeric compound

被引：1
|
作者：
Meng, Fa-Yan
Dong, Wu-Heng
Ng, Seik Weng [1 ]
机构：
[1] Univ Malaya, Dept Chem, Kuala Lumpur 50603, Malaysia
[2] Huangshi Inst Technol, Sch Chem & Mat Engn, Huangshi 435003, Peoples R China
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2007年 / 63卷
关键词：
CRYSTAL-STRUCTURES; COMPLEXES; NICKEL; COBALT; ACID;
D O I：
10.1107/S160053680704055X
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The succinate dianion in the title 1:2 zinc succinate 1,3-bis(benzimidazol-2-yl) benzene adduct, [ Zn(C4H4O4)(C20H14N4)(2)], chelates the Zn atom, which is datively bonded to two of the N- heterocycles in a tetrahedral geometry. The Zn atom and the succinate dianion lie on a twofold rotation axis. The amino - NH group of one heterocycle forms a weak intramolecular hydrogen bond to the carbonyl O atom; that of the second heterocycle engages in an intermolecular N-H center dot center dot center dot N interaction resulting in a linear chain structure.
引用
收藏
页码：M2398 / U1375
页数：11
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