The effect of an acylphosphine ligand on the rhodium-catalyzed hydrosilylation of alkenes

被引：14
|
作者：
Li, Jiayun [1 ]
Yang, Chuang [1 ]
Bai, Ying [1 ]
Yang, Xiaoling [1 ]
Liu, Yu [1 ]
Peng, Jiajian [1 ]
机构：
[1] Hangzhou Normal Univ, Minist Educ, Key Lab Organosilicon Chem & Mat Technol, Hangzhou 311121, Zhejiang, Peoples R China
来源：
JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2018年 / 855卷
关键词：
Acylphosphine; Hydrosilylation; Rhodium complex; OLEFIN POLYMERIZATION CATALYSTS; TRANSITION-METAL CATALYSTS; PHOSPHORUS LIGANDS;
D O I：
10.1016/j.jorganchem.2017.12.004
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
We synthesized a series of acylphosphines and investigated the hydrosilylation of alkenes that were catalyzed using RhCl3/acylphosphine. The results indicated that RhCl3/(diphenylphosphino) (phenyl) methanone exhibited higher activity as well as higher levels of beta-adduct selectivity. (C) 2017 Elsevier B.V. All rights reserved.
引用
收藏
页码：7 / 11
页数：5
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