Ion-solvent and ion-ion interactions at high concentration LiClO4 solutions in acetone

被引：0

作者：

Xuan, XP ^{[1
]}

Wang, JJ ^{[1
]}

Zhao, Y ^{[1
]}

Zhuo, KL ^{[1
]}

机构：

[1] Henan Normal Univ, Sch Chem & Environm Sci, Xinxiang 453007, Peoples R China

来源：

ACTA CHIMICA SINICA | 2005年 / 63卷 / 18期

关键词：

lithium perchlorate; acetone; ion solvation; ion association; raman spectroscopy; infrared spectroscopy;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The Infrared and Raman spectra of LiClO4/acetone solutions have been investigated from diluted to high concentrations. It was found that the C=O and C-C stretches of acetone were very sensitive to the interaction between Li+ and acetone molecules. Apparent solvation numbers of 1.9 similar to 3.4 for Li+ have been inferred at different molalities of LiClO4 and the carbonyl group was suggested to be the main bonding site. The ClO4- bands reveal the evidence for the presence of contact ion pair and its dimer. The association constants of LiClO4 in acetone has been calculated and compared with the data obtained from conductivity measurements.

引用

页码：1693 / 1698

页数：6

共 18 条

[1] Ion solvation and ion association in lithium trifluoromethanesulfonate solutions in three aprotic solvents.: An FT-Raman spectroscopic study [J].

Alía, JM ;

Edwards, HGM .

VIBRATIONAL SPECTROSCOPY, 2000, 24 (02) :185-200

[2] FT-Raman spectroscopic study of ionic association and solvation in acrylonitrile solutions of calcium and magnesium perchlorate [J].

Alia, JM ;

Edwards, HGM ;

Moore, J .

JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS, 1996, 92 (07) :1187-1196

[3]

AURBACH D, 1999, NONAQUEOUS ELECTROCH, pCH2

[4] VIBRATIONAL STUDIES OF LITHIUM PERCHLORATE IN PROPYLENE CARBONATE SOLUTIONS [J].

BATTISTI, D ;

NAZRI, GA ;

KLASSEN, B ;

AROCA, R .

JOURNAL OF PHYSICAL CHEMISTRY, 1993, 97 (22) :5826-5830

[5] Aggregation of perchlorates in aprotic donor solvents .2. Alkaline-earth metal perchlorates [J].

Chabanel, M ;

Touaj, K .

JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS, 1996, 92 (21) :4207-4213

[6] Aggregation of perchlorates in aprotic donor solvents .1. Lithium and sodium perchlorates [J].

Chabanel, M ;

Legoff, D ;

Touaj, K .

JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS, 1996, 92 (21) :4199-4205

[7] VIBRATIONAL ANALYSIS OF ACETONE ACETALDEHYDE AND FORMALDEHYDE [J].

COSSEE, P ;

SCHACHTS.JH .

JOURNAL OF CHEMICAL PHYSICS, 1966, 44 (01) :97-&

[8] VIBRATIONAL SPECTRA AND ASSIGNMENT OF ACETONE ALPHAALPHAALPHA ACETONE-D3 AND ACETONE-D6 [J].

DELLEPIANE, G ;

OVEREND, J .

SPECTROCHIMICA ACTA, 1966, 22 (04) :593-+

[9] A RAMAN SPECTRAL STUDY OF SOLVATION AND ION ASSOCIATION IN THE SYSTEMS LIASF6/CH3CO2CH3 AND LIASF6/HCO2CH3 [J].

DENG, ZY ;

IRISH, DE .

CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1991, 69 (11) :1766-1773

[10] RAMAN SPECTRAL STUDIES OF ION ASSOCIATION AND SOLVATION IN SOLUTIONS OF LIASF6-ACETONE [J].

DENG, ZY ;

IRISH, DE .

JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS, 1992, 88 (19) :2891-2896

← 1 2 →