Ultrastrong nanocrystalline steel with exceptional thermal stability and radiation tolerance

被引:132
作者
Du, Congcong [1 ]
Jin, Shenbao [2 ]
Fang, Yuan [3 ]
Li, Jin [4 ]
Hu, Shenyang [5 ]
Yang, Tingting [1 ]
Zhang, Ying [1 ]
Huang, Jianyu [1 ]
Sha, Gang [2 ]
Wang, Yugang [3 ]
Shang, Zhongxia [4 ]
Zhang, Xinghang [4 ]
Sun, Baoru [1 ]
Xin, Shengwei [1 ]
Shen, Tongde [1 ]
机构
[1] Yanshan Univ, Clean Nano Energy Ctr, State Key Lab Metastable Mat Sci & Technol, Qinhuangdao 066004, Peoples R China
[2] Nanjing Univ Sci & Technol, Dept Mat Sci & Engn, Nanjing 210094, Jiangsu, Peoples R China
[3] Peking Univ, Ctr Appl Phys & Technol, State Key Lab Nucl Phys & Technol, Beijing 100871, Peoples R China
[4] Purdue Univ, Sch Mat Engn, W Lafayette, IN 47907 USA
[5] Pacific Northwest Natl Lab, POB 999, Richland, WA 99352 USA
基金
中国国家自然科学基金; 美国能源部;
关键词
GRAIN-SIZE STABILIZATION; FERRITIC STEELS; IN-SITU; IRRADIATION; DAMAGE; HELIUM; MICROSTRUCTURE; ALLOYS; DEFECT; CHALLENGES;
D O I
10.1038/s41467-018-07712-x
中图分类号
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号
07 ; 0710 ; 09 ;
摘要
Nanocrystalline (NC) metals are stronger and more radiation-tolerant than their coarse-grained (CG) counterparts, but they often suffer from poor thermal stability as nanograins coarsen significantly when heated to 0.3 to 0.5 of their melting temperature (T-m). Here, we report an NC austenitic stainless steel (NC-SS) containing 1 at% lanthanum with an average grain size of 45 nm and an ultrahigh yield strength of similar to 2.5 GPa that exhibits exceptional thermal stability up to 1000 degrees C (0.75 T-m). In-situ irradiation to 40 dpa at 450 degrees C and ex-situ irradiation to 108 dpa at 600 degrees C produce neither significant grain growth nor void swelling, in contrast to significant void swelling of CG-SS at similar doses. This thermal stability is due to segregation of elemental lanthanum and (La, O, Si)-rich nanoprecipitates at grain boundaries. Microstructure dependent cluster dynamics show grain boundary sinks effectively reduce steady-state vacancy concentrations to suppress void swelling upon irradiation.
引用
收藏
页数:9
相关论文
共 62 条
[51]  
SMITH CS, 1948, T AM I MIN MET ENG, V175, P15
[52]   Superior radiation-resistant nanoengineered austenitic 304L stainless steel for applications in extreme radiation environments [J].
Sun, C. ;
Zheng, S. ;
Wei, C. C. ;
Wu, Y. ;
Shao, L. ;
Yang, Y. ;
Hartwig, K. T. ;
Maloy, S. A. ;
Zinkle, S. J. ;
Allen, T. R. ;
Wang, H. ;
Zhang, X. .
SCIENTIFIC REPORTS, 2015, 5
[53]   Probing grain boundary sink strength at the nanoscale: Energetics and length scales of vacancy and interstitial absorption by grain boundaries in α-Fe [J].
Tschopp, M. A. ;
Solanki, K. N. ;
Gao, F. ;
Sun, X. ;
Khaleel, M. A. ;
Horstemeyer, M. F. .
PHYSICAL REVIEW B, 2012, 85 (06)
[54]   Ideal sinks are not always ideal: Radiation damage accumulation in nanocomposites [J].
Uberuaga, Blas Pedro ;
Choudhury, Samrat ;
Caro, Alfredo .
JOURNAL OF NUCLEAR MATERIALS, 2015, 462 :402-408
[55]   Microstructural observation and tensile properties of ODS-304 austenitic steel [J].
Wang, Man ;
Zhou, Zhangjian ;
Sun, Hongying ;
Hu, Helong ;
Li, Shaofu .
MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING, 2013, 559 :287-292
[56]   ALLOY THERMODYNAMICS IN NANOSTRUCTURES [J].
WEISSMULLER, J .
JOURNAL OF MATERIALS RESEARCH, 1994, 9 (01) :4-7
[57]  
WEISSMULLER J, 1993, NANOSTRUCT MATER, V3, P261, DOI 10.1016/0965-9773(93)90088-S
[58]   Radiation damage in helium ion irradiated nanocrystalline Fe [J].
Yu, K. Y. ;
Liu, Y. ;
Sun, C. ;
Wang, H. ;
Shao, L. ;
Fu, E. G. ;
Zhang, X. .
JOURNAL OF NUCLEAR MATERIALS, 2012, 425 (1-3) :140-146
[59]   Radiation damage in nanostructured materials [J].
Zhang, Xinghang ;
Hattar, Khalid ;
Chen, Youxing ;
Shao, Lin ;
Li, Jin ;
Sun, Cheng ;
Yu, Kaiyuan ;
Li, Nan ;
Taheri, Mitra L. ;
Wang, Haiyan ;
Wang, Jian ;
Nastasi, Michael .
PROGRESS IN MATERIALS SCIENCE, 2018, 96 :217-321
[60]   Enhanced thermal stability of nanograined metals below a critical grain size [J].
Zhou, X. ;
Li, X. Y. ;
Lu, K. .
SCIENCE, 2018, 360 (6388) :526-529