Separation of Heavy Metal Ions from Petroleum Ash Liquor Using Organic Resins and FT-IR Study of the Process

被引：5
作者：
Abd El-Hamid, A. M. [1 ]
Zahran, M. A. [2 ]
Ahmed, Y. M. Z. [3 ]
El-Sheikh, S. M. [3 ]
机构：
[1] Nucl Mat Author, Cairo 11381, Egypt
[2] Menuofiya Univ, Fac Sci, Chem Dept, Menuofiya 32511, Egypt
[3] Cent Met Res & Dev, Adv Mat Dept, Cairo 11421, Egypt
来源：
RADIOCHEMISTRY | 2020年 / 62卷 / 02期
关键词：
Fourier transform IR spectroscopy; separation; heavy metal ions; Dowex resin; Amberlite resin; petroleum ash; NICKEL SULFIDE; ZIRCONIUM; HAFNIUM; REDUCTION;
D O I：
10.1134/S1066362220020125
中图分类号：
O65 [分析化学];
学科分类号：
070302 ; 081704 ;
摘要：
Heavy metal ions such as hafnium, zirconium, vanadium, nickel, iron, and uranium were separated from petroleum ash leach liquor using ion-exchange resins Dowex 1x8, A2S3B8, and Amberlite (IRA-420). The separation was studied using Fourier transform IR spectroscopy (FT-IR) to confirm the adsorption of the metal ions onto the organic resins. Possible reactions between the metal ions and organic resins were suggested on the basis of the FT-IR spectra. The results show that the Dowex resin takes up U, Hf, and Zr most efficiently. This fact can be attributed to the ability of the Dowex resin to reduce both vanadium(V) and iron(III) metal ions to the lower valence state. This reduction facilitates the absorption of U, Hf, and Zr ions. The results obtained by ICP-OES and FT-IR are compared.
引用
收藏
页码：243 / 250
页数：8
相关论文
共 23 条
  • [11] Controlled nickel sulfide precipitation using gaseous hydrogen sulfide
    Karbanee, Nazneen
    Van Hille, Robert. P.
    Lewis, Alison E.
    [J]. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2008, 47 (05) : 1596 - 1602
  • [12] Ling Y.W., 2016, HYDROMETALLURGY, V160, P12, DOI [10.1016/j.hydromet.2015.11.013, DOI 10.1016/J.HYDROMET.2015.11.013]
  • [13] Mani P., 2009, Rasayan J. Chem, V2, P307
  • [14] Periasamy A., 2009, RASAYAN J CHEM, V2, P981
  • [15] Pravin U.S., 2011, OPEN J PHYS CHEM, V1, P45, DOI [10.4236/ojpc.2011.12007, DOI 10.4236/OJPC.2011.12007]
  • [16] Raju B., 2013, J RADIOANAL NUCL CHE, V295, P1537, DOI [10.1007/s10967-012-1941-5, DOI 10.1007/S10967-012-1941-5]
  • [17] Shahab S., 2008, J HAZARD MATER, V156, P583, DOI [10.1016/j.jhazmat.2007.12.061, DOI 10.1016/J.JHAZMAT.2007.12.061]
  • [18] Separation of zirconium and hafnium using Diphonix® chelating ion-exchange resin
    Smolik, M.
    Jakobik-Kolon, A.
    Poranski, M.
    [J]. HYDROMETALLURGY, 2009, 95 (3-4) : 350 - 353
  • [19] Susanta L., 2000, APPL RADIAT ISOTOPES, V52, P1399, DOI [10.1016/S0969-8043(99)00167-0, DOI 10.1016/S0969-8043(99)00167-0]
  • [20] Separation of zirconium and hafnium by solvent extraction using mixture of TBP and Cyanex 923
    Taghizadeh, M.
    Ghanadi, M.
    Zolfonoun, E.
    [J]. JOURNAL OF NUCLEAR MATERIALS, 2011, 412 (03) : 334 - 337
123