Air-Stable Bifunctional HASPO Preligands for Metal-Catalyzed Cross-Couplings and Direct C-H Bond Arylations

被引：79

作者：

Ackermann, Lutz ^{[1
]}

机构：

[1] Univ Gottingen, Inst Organ & Biomol Chem, D-37077 Gottingen, Germany

来源：

ISRAEL JOURNAL OF CHEMISTRY | 2010年 / 50卷 / 5-6期

关键词：

arylation; C-H bond activation; cross-coupling; palladium; preligands; PALLADIUM-PHOSPHINOUS ACID; BIPHENYLENE-SUBSTITUTED RUTHENOCENYLPHOSPHINE; SUZUKI-MIYAURA; GRIGNARD-REAGENTS; F ACTIVATION; ARYL CHLORIDES; COORDINATION CHEMISTRY; EFFICIENT SYNTHESIS; ALKENYL HALIDES; C-3; ARYLATION;

D O I：

10.1002/ijch.201000043

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Progress in the use of heteroatom-substituted secondary phosphine oxides (HASPO) as bifunctional preligands in transition-metal-catalyzed cross-coupling reactions as well as C-H bond functionalizations with challenging substrates is summarized herein until July 2010.

引用

页码：652 / 663

页数：12

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