Air-Stable Bifunctional HASPO Preligands for Metal-Catalyzed Cross-Couplings and Direct C-H Bond Arylations

被引：77
作者：
Ackermann, Lutz [1 ]
机构：
[1] Univ Gottingen, Inst Organ & Biomol Chem, D-37077 Gottingen, Germany
来源：
ISRAEL JOURNAL OF CHEMISTRY | 2010年 / 50卷 / 5-6期
关键词：
arylation; C-H bond activation; cross-coupling; palladium; preligands; PALLADIUM-PHOSPHINOUS ACID; BIPHENYLENE-SUBSTITUTED RUTHENOCENYLPHOSPHINE; SUZUKI-MIYAURA; GRIGNARD-REAGENTS; F ACTIVATION; ARYL CHLORIDES; COORDINATION CHEMISTRY; EFFICIENT SYNTHESIS; ALKENYL HALIDES; C-3; ARYLATION;
D O I：
10.1002/ijch.201000043
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Progress in the use of heteroatom-substituted secondary phosphine oxides (HASPO) as bifunctional preligands in transition-metal-catalyzed cross-coupling reactions as well as C-H bond functionalizations with challenging substrates is summarized herein until July 2010.
引用
收藏
页码：652 / 663
页数：12
相关论文
共 50 条
  • [21] Recent advances in transition metal-catalyzed C-H bond functionalization of ferrocene derivatives
    Lopez, Luis A.
    Lopez, Enol
    DALTON TRANSACTIONS, 2015, 44 (22) : 10128 - 10135
  • [22] Exploiting the C-H bond in metal-catalyzed C-C bond-forming reactions
    Schnuerch, Michael
    ARKIVOC, 2015, : 212 - 243
  • [23] 8-Aminoquinoline: A Powerful Directing Group in Metal-Catalyzed Direct Functionalization of C-H Bonds
    Corbet, Matthieu
    De Campo, Floryan
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2013, 52 (38) : 9896 - 9898
  • [24] Transition-Metal-Catalyzed Direct Arylation of (Hetero)Arenes by C-H Bond Cleavage
    Ackermann, Lutz
    Vicente, Ruben
    Kapdi, Anant R.
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2009, 48 (52) : 9792 - 9826
  • [25] Sterically demanding, zwitterionic trialkylphosphonium sulfonates as air-stable ligand precursors for efficient palladium-catalyzed cross-couplings of aryl bromides and chlorides
    Brown, William S.
    Boykin, D'Ariel D.
    Sonnier, M. Quentin, Jr.
    Clark, William D.
    Brown, Fallon V.
    Shaughnessy, Kevin H.
    SYNTHESIS-STUTTGART, 2008, (12): : 1965 - 1970
  • [26] Ruthenium-Catalyzed C-H Bond Functionalizations of 1,2,3-Triazol-4-yl-Substituted Arenes: Dehydrogenative Couplings Versus Direct Arylations
    Ackermann, Lutz
    Novak, Petr
    Vicente, Ruben
    Pirovano, Valentina
    Potukuchi, Harish K.
    SYNTHESIS-STUTTGART, 2010, (13): : 2245 - 2253
  • [27] Transition metal-catalyzed C-H bond functionalization in multicomponent reactions: a tool toward molecular diversity
    Wan, Jie-Ping
    Gan, Lu
    Liu, Yunyun
    ORGANIC & BIOMOLECULAR CHEMISTRY, 2017, 15 (43) : 9031 - 9043
  • [28] Transition metal-catalyzed olefin arylation via C-H bond activation of arenes
    Matsumoto, Takaya
    CATALYSIS SURVEYS FROM ASIA, 2007, 11 (1-2) : 31 - 48
  • [29] Transition Metal-Catalyzed Carbonylative C-H Bond Functionalization of Arenes and C(sp3)-H Bond of Alkanes
    Gadge, Sandip T.
    Gautam, Prashant
    Bhanage, Bhalchandra M.
    CHEMICAL RECORD, 2016, 16 (02) : 835 - 856
  • [30] Nickel-Catalyzed Direct C-H/C-O Cross Couplings Generating Fluorobenzenes and Heteroarenes
    Xiao, Jing
    Chen, Tieqiao
    Han, Li-Biao
    ORGANIC LETTERS, 2015, 17 (04) : 812 - 815
12345