C-H and C-S Activations of Quinoline-Functionalized Thiophenes by Platinum Complexes

被引：33

作者：

Tan, Runyu ^{[1
]}

Song, Datong ^{[1
]}

机构：

[1] Univ Toronto, Davenport Chem Res Lab, Dept Chem, Toronto, ON M5S 3H6, Canada

来源：

ORGANOMETALLICS | 2011年 / 30卷 / 06期

基金：

加拿大自然科学与工程研究理事会;

关键词：

BOND-CLEAVAGE; CARBON-SULFUR; TRIS(TRIETHYLPHOSPHINE)PLATINUM(0); (C5ME5)RH(C2H4)2; COORDINATION; REACTIVITY; INSERTION; DENSITY;

D O I：

10.1021/om101171s

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

We synthesized and characterized two ligands, 2-(quinolin-8-yl)thiophene (1a) and 3-(quinolin-8-yl)thiophene (1b). The selective C-H activation of the thiophene moieties was achieved by reacting 1a or, 1b and [Pt(CH3)(2)(SMe2)](2). We observed eta(2)-thiophene intermediates during the course of the reactions. The selective C-S bond activation of the thiophene moieties was observed after reacting 1a or 1b and [Pt(dippe)H](2). DFT calculations were performed to elucidate the regioselectivity of C-S activations.

引用

页码：1637 / 1645

页数：9

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