Highly selective conversion of H2S-CO2 to syngas by combination of non-thermal plasma and MoS2/Al2O3

被引：19

作者：

Zhao, Lu ^{[1
]}

Liu, Xiaozhan ^{[1
]}

Mu, Xiaoliang ^{[1
]}

Li, Ying ^{[1
]}

Fang, Kegong ^{[1
]}

机构：

[1] Chinese Acad Sci, Inst Coal Chem, State Key Lab Coal Convers, Taiyuan 030001, Shanxi, Peoples R China

来源：

JOURNAL OF CO2 UTILIZATION | 2020年 / 37卷

基金：

中国国家自然科学基金;

关键词：

Syngas; CO2; H2S; DBD plasma; MoS2/Al2O3; CO2; HYDROGENATION; CATALYST; DISCHARGE; SULFIDE; DECOMPOSITION; REACTOR; SULFUR; HYDROCARBONS; PERFORMANCE; REDUCTION;

D O I：

10.1016/j.jcou.2019.11.021

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The highly selective conversion of H2S-CO2 to syngas (a mixture of H-2 and CO), which assisted by non-thermal plasma and MoS2/Al2O3 hybrid system, was obtained at low temperature and atmospheric pressure. The effects of reaction conditions, including the specific energy input (SEI), feed flow rate, feed gas composition (H2S/CO2 molar ratio), and MoS2 loading were carefully investigated. The 50-h-long runs indicate that MoS2/Al2O3 was stable in the course of simultaneous H2S-CO2 conversion into syngas with excellent reaction properties. High CO2 conversion (>60 %) and almost full H2S conversion (98-100 %) can be achieved. The non-thermal plasma combined with MoS2/Al2O3 offers a novel and energy-efficient strategy to produce syngas from concomitant H2S-CO2 acid gases with great value for detoxifying H2S and reducing CO2 emissions.

引用

页码：45 / 54

页数：10

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