Electrochemical reduction of carbon dioxide on tin, zinc, and their alloys

被引：0
|
作者：
Cherashev, AF [1 ]
Khrushch, AP [1 ]
机构：
[1] Russian Acad Sci, Inst Chem Phys, Chernogolovka 142432, Moscow Oblast, Russia
来源：
RUSSIAN JOURNAL OF ELECTROCHEMISTRY | 1998年 / 34卷 / 05期
关键词：
D O I：
暂无
中图分类号：
O646 [电化学、电解、磁化学];
学科分类号：
081704 ;
摘要：
Kinetics of the electrochemical reduction of carbon dioxide on tin, zinc, and their alloys are studied. The Tafel dependences obtained suggest that the process involves two stages: (a) electrochemical discharge of ions of an alkali metal present in the supporting electrolyte, which forms an intermetallic compound with the cathode material, and (b) subsequent chemical interaction of the compound with carbon dioxide, The scheme proposed for the process explains why the reduction rate depends on the electrode material.
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页码：410 / 417
页数：8
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