Synthesis of Allenes via Gold-Catalyzed Intermolecular Reaction of Propargylic Alcohols and Aromatic Compounds

被引：40

作者：

Xu, Cheng-Fu ^{[1
]}

Xu, Mei ^{[1
]}

Yang, Liu-Qing ^{[1
]}

Li, Chuan-Ying ^{[1
]}

机构：

[1] Zhejiang Sci Tech Univ, Dept Chem, Hangzhou 310018, Zhejiang, Peoples R China

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2012年 / 77卷 / 06期

基金：

中国国家自然科学基金;

关键词：

ONE-POT SYNTHESIS; ENANTIOSELECTIVE SYNTHESIS; 1,3-DISUBSTITUTED ALLENES; OLEFINATION; SUBSTITUTION; ALDEHYDES; INDOLES; COMPLEX; KETONES; ALKYNES;

D O I：

10.1021/jo300147u

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Functionalized allenes are efficiently synthesized in moderate to high yield from gold-catalyzed intermolecular reaction of propargylic alcohols and aromatic compounds. The user-friendly process could be conducted under mild reaction conditions with easily accessible starting materials.

引用

页码：3010 / 3016

页数：7

共 50 条

[41] Synthesis of Allenamides and Structurally Related Compounds by a Gold-Catalyzed Hydride Shift Process [J].

Zhao, Qing ;

Gagosz, Fabien .

ADVANCED SYNTHESIS & CATALYSIS, 2017, 359 (18) :3108-3113

[42] The Synthesis of Aromatic Heterocycles from Propargylic Compounds [J].

Wen Jia-Jie ;

Zhu, Yu ;

Zhan, Zhuang-Ping .

ASIAN JOURNAL OF ORGANIC CHEMISTRY, 2012, 1 (02) :108-129

[43] HFIP-Catalyzed Difluoroalkylation of Propargylic Alcohols to Access Tetrasubstituted Difluoroalkyl Allenes [J].

Li, Jinshan ;

Xi, Wenxue ;

Liu, Saimei ;

Ruan, Chenxi ;

Zheng, Xiaochun ;

Yang, Jianguo ;

Wang, Lei ;

Wang, Zhiming .

ORGANIC LETTERS, 2021, 23 (18) :7264-7269

[44] Gold-Catalyzed Synthesis of Iodofulvenes [J].

Noesel, Pascal ;

Lauterbach, Tobias ;

Rudolph, Matthias ;

Rominger, Frank ;

Hashmi, A. Stephen K. .

CHEMISTRY-A EUROPEAN JOURNAL, 2013, 19 (26) :8634-8641

[45] Stereoselective synthesis of tetracyclic indolines via gold-catalyzed cascade cyclization reactions [J].

Cera, Gianpiero ;

Crispino, Pasquale ;

Monari, Magda ;

Bandini, Marco .

CHEMICAL COMMUNICATIONS, 2011, 47 (27) :7803-7805

[46] Recent Advances in the Synthesis of Heterocycles via Gold-catalyzed Cascade Reactions: A Review [J].

Gao, Feng ;

Zhou, Yu ;

Liu, Hong .

CURRENT ORGANIC CHEMISTRY, 2017, 21 (15) :1530-1566

[47] Gold-Catalyzed Synthesis of 3-Arylindoles via Annulation of Nitrosoarenes and Alkynes [J].

Murru, Siva ;

Gallo, August A. ;

Srivastava, Radhey S. .

ACS CATALYSIS, 2011, 1 (01) :29-31

[48] Asymmetric synthesis of heteroaryl atropisomers via a gold-catalyzed cycloisomerization-amination cascade reaction [J].

Guo, Rui ;

Li, Kang-Nan ;

Liu, Bin ;

Zhu, Hua-Jie ;

Fan, Yu-Meng ;

Gong, Liu-Zhu .

CHEMICAL COMMUNICATIONS, 2014, 50 (41) :5451-5454

[49] Enantioselective Gold-Catalyzed Synthesis of Polycyclic Indolines [J].

Cera, Gianpiero ;

Chiarucci, Michel ;

Mazzanti, Andrea ;

Mancinelli, Michele ;

Bandini, Marco .

ORGANIC LETTERS, 2012, 14 (05) :1350-1353

[50] An Efficient [2+2+1] Synthesis of 2,5-Disubstituted Oxazoles via Gold-Catalyzed Intermolecular Alkyne Oxidation [J].

He, Weimin ;

Li, Chaoqun ;

Zhang, Liming .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2011, 133 (22) :8482-8485

← 1 2 3 4 5 →