Transmetallation between Metal-Only Lewis Pairs: a new rhodium alane complex

被引：17

作者：

Bauer, Juergen ^{[1
]}

Braunschweig, Holger ^{[1
]}

Radacki, Krzysztof ^{[1
]}

机构：

[1] Univ Wurzburg, Inst Anorgan Chem, D-97074 Wurzburg, Germany

来源：

CHEMICAL COMMUNICATIONS | 2012年 / 48卷 / 84期

关键词：

X-RAY CRYSTAL; MOLECULAR-STRUCTURE; BASES; PLATINUM; CHLORIDE; ADDUCTS; BONDS;

D O I：

10.1039/c2cc35248f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In this communication, synthesis of a rhodium alane Lewis adduct, [Cp(Me3P)(2)Rh -> AlCl3], is reported. Given that direct synthesis using aluminium trichloride failed, a convenient transmetallation reaction was applied. The new MOLP was analysed by single crystal X-ray diffraction, multinuclear NMR spectroscopy and density functional theory calculations.

引用

页码：10407 / 10409

页数：3

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