Experimental and computational studies of pyridine-assisted post-synthesis modified air stable covalent-organic frameworks

被引：73

作者：

Du, Yi ^{[1
]}

Mao, Kanmi ^{[1
]}

Kamakoti, Preeti ^{[1
]}

Ravikovitch, Peter ^{[1
]}

Paur, Charanjit ^{[1
]}

Cundy, Stephen ^{[1
]}

Li, Quanchang ^{[1
]}

Calabro, David ^{[1
]}

机构：

[1] ExxonMobil Res & Engn Co, Corp Strateg Res Lab, Annandale, NJ 08801 USA

来源：

CHEMICAL COMMUNICATIONS | 2012年 / 48卷 / 38期

关键词：

NMR; CRYSTALLINE; SILICA; LEWIS; ACID; STORAGE;

D O I：

10.1039/c2cc30781b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Pyridine-modified COF-10 exhibits enhanced stability in humid air relative to un-modified COF-10. Solid state NMR and computational studies were used to probe the nature of pyridine interactions with the framework. We propose two models for pyridine-framework interactions with different stabilities.

引用

页码：4606 / 4608

页数：3

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