An experimental study on the influence of trace impurities on ionization of atmospheric noble gas dielectric barrier discharges

被引:16
作者
Klute, F. D. [1 ]
Schuetz, A. [1 ]
Michels, A. [1 ]
Vadla, C. [2 ]
Veza, D. [3 ]
Horvatic, V. [2 ]
Franzke, J. [1 ]
机构
[1] ISAS Leibniz Inst Analyt Wissensch, Bunsen Kirchhoff Str 11, D-44139 Dortmund, Germany
[2] Inst Phys, Bijenicka 46, Zagreb 10000, Croatia
[3] Univ Zagreb, Fac Sci, Dept Phys, Bijenicka 32, Zagreb 10000, Croatia
关键词
EMISSION-SPECTROMETRY; MASS-SPECTROMETRY; SOFT IONIZATION; PLASMA; RADIATION;
D O I
10.1039/c6an01352j
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
While the influence of trace impurities in noble gas discharges is well established in theoretical work, experimental approaches are difficult. Particularly the effects of trace concentrations of N-2 on He discharges are complicated to investigate due to the fact that for He 5.0 the purity of He is only 99.999%. This corresponds to a residual concentration of 10 ppm, thereof 3 ppm of N-2, in He. Matters are made difficult by the fact that He DBD plasmajets are normally operated under an ambient atmosphere, which has a high abundance of N-2. This work tackles these problems from two sides. The first approach is to operate a DBD plasmajet under a quasi-controlled He atmosphere, therefore diminishing the effect of atmospheric N-2 and making a defined contamination with N-2 possible. The second approach is using Ar as the operating gas and introducing propane (C3H8) as a suitable substitute impurity like N-2 in He. As will be shown both discharges in either He or Ar, with their respective impurity show the same qualitative behaviour.
引用
收藏
页码:5842 / 5848
页数:7
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