Conversion of methane to syngas by a membrane-based oxidation-reforming process

被引：145

作者：

Chen, CS ^{[1
]}

Feng, SJ

Ran, S

Zhu, DC

Liu, W

Bouwmeester, HJM

机构：

[1] Univ Sci & Technol China, Dept Mat Sci & Engn, Lab Adv Funct Mat & Devices, Anhua 230026, Peoples R China

[2] Univ Twente, Fac Sci & Technol & MESA, Lab Inorgan Mat Sci, NL-7500 AE Enschede, Netherlands

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2003年 / 42卷 / 42期

关键词：

ceramics; membranes; methane; oxygen; syngas;

D O I：

10.1002/anie.200351085

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Two processes in one space: Methane, the main component of natural gas, can be converted into syngas efficiently in a two-stage oxygen-permeable ceramic membrane reactor by means of integrated oxidation and reforming processes (see picture). This could be a cheaper alternative to the current steam-reforming of methane.

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收藏

页码：5196 / 5198

页数：3

相关论文

共 13 条

[1] SELECTIVE OXIDATION OF METHANE TO SYNTHESIS GAS-USING TRANSITION-METAL CATALYSTS [J].

ASHCROFT, AT ;

CHEETHAM, AK ;

FOORD, JS ;

GREEN, MLH ;

GREY, CP ;

MURRELL, AJ ;

VERNON, PDF .

NATURE, 1990, 344 (6264) :319-321

[2] Ceramic membrane reactor for converting methane to syngas [J].

Balachandran, U ;

Dusek, JT ;

Maiya, PS ;

Ma, B ;

Mieville, RL ;

Kleefisch, MS ;

Udovich, CA .

CATALYSIS TODAY, 1997, 36 (03) :265-272

[3]

Chen C.S, 2001, ANGEW CHEM, V113, P806

[4]

Chen CS, 2001, ANGEW CHEM INT EDIT, V40, P784, DOI 10.1002/1521-3773(20010216)40:4<784::AID-ANIE7840>3.0.CO

[5]

2-H

[6] PARTIAL OXIDATION OF METHANE TO CARBON-MONOXIDE AND HYDROGEN OVER A NI/AL2O3 CATALYST [J].

DISSANAYAKE, D ;

ROSYNEK, MP ;

KHARAS, KCC ;

LUNSFORD, JH .

JOURNAL OF CATALYSIS, 1991, 132 (01) :117-127

[7] Prospects and problems of dense oxygen permeable membranes [J].

Hendriksen, PV ;

Larsen, PH ;

Mogensen, M ;

Poulsen, FW ;

Wiik, K .

CATALYSIS TODAY, 2000, 56 (1-3) :283-295

[8] PRODUCTION OF SYNGAS BY DIRECT CATALYTIC-OXIDATION OF METHANE [J].

HICKMAN, DA ;

SCHMIDT, LD .

SCIENCE, 1993, 259 (5093) :343-346

[9] Cobalt-containing catalysts for the high-temperature combustion of methane [J].

Milt, VG ;

Ulla, MA ;

Lombardo, EA .

CATALYSIS LETTERS, 2000, 65 (1-3) :67-73

[10] Investigation of the permeation behavior and stability of a Ba0.5Sr0.5Co0.8Fe0.2O3-δ oxygen membrane [J].

Shao, ZP ;

Yang, WS ;

Cong, Y ;

Dong, H ;

Tong, JH ;

Xiong, GX .

JOURNAL OF MEMBRANE SCIENCE, 2000, 172 (1-2) :177-188