An indium-based microporous metal-organic framework with unique three-way rod-shaped secondary building units for efficient methane and hydrogen storage

被引：12

作者：

Cui, Hui ^{[1
,2
]}

Ye, Yingxiang ^{[3
]}

Lin, Ruibiao ^{[4
]}

Shi, Yanshu ^{[1
]}

Alothman, Zeid A. ^{[5
]}

Alduhaish, Osamah ^{[5
]}

Wang, Bin ^{[3
]}

Zhang, Jian ^{[6
]}

Chen, Banglin ^{[1
]}

机构：

[1] Univ Texas San Antonio, Dept Chem, One UTSA Circle, San Antonio, TX 78249 USA

[2] Argonne Natl Lab, Phys Div, Lemont, IL 60439 USA

[3] Univ North Texas Denton, Dept Chem, Denton, TX 76201 USA

[4] Sun Yat Sen Univ, Sch Chem, MOE Key Lab Bioinorgan & Synthet Chem, Guangzhou 510006, Peoples R China

[5] King Saud Univ, Coll Sci, Chem Dept, Riyadh 11451, Saudi Arabia

[6] Lawrence Berkeley Natl Lab, Mol Foundry, Berkeley, CA 94720 USA

来源：

INORGANIC CHEMISTRY FRONTIERS | 2022年 / 9卷 / 24期

关键词：

PORE GEOMETRY; CAPACITY; MOFS; ADSORPTION; TOPOLOGY; SIZE;

D O I：

10.1039/d2qi01956f

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A novel microporous indium-based MOF material with unique 3-way rod-shaped secondary building units (SBUs), UTSA-22, was reported and exhibited high methane (CH4) and hydrogen (H-2) storage. At 298 K and 65 bar, the total CH4 volumetric uptake of UTSA-22 is 174 cm(3)(STP) cm(-3). Moreover, UTSA-22 shows a high CH4 working capacity of 146 cm(3)(STP) cm(-3) in a pressure range of 5-65 bar at 298 K. In addition, UTSA-22 shows a high H-2 gravimetric storage capacity (1.2 wt%) at 298 K and 100 bar.

引用

页码：6527 / 6533

页数：7

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