Photocatalytic and antimicrobial activities of chitosan-TiO2 nanocomposite

被引:140
作者
Karthikeyan, K. T. [1 ,2 ]
Nithya, A. [1 ]
Jothivenkatachalam, K. [1 ]
机构
[1] Anna Univ, Bharathidasan Inst Technol, Dept Chem, Tiruchirappalli 620024, Tamil Nadu, India
[2] MAM Coll Engn, Dept Chem, Tiruchirappalli, Tamil Nadu, India
关键词
Chitosan; Titanium dioxide; Photocatalyst; Antimicrobial agent; TIO2; NANOPARTICLES; GOLD NANOPARTICLES; IRRADIATION; REMOVAL; DYES; BIOSYNTHESIS; FILMS;
D O I
10.1016/j.ijbiomac.2017.03.121
中图分类号
Q5 [生物化学]; Q7 [分子生物学];
学科分类号
071010 ; 081704 ;
摘要
Chitcisan, a natural polysaccharide widely used for various biological applications due to their potential benefits. Incorporation of biomaterials with semiconductor has been exploited for waste water treatment and biological applications due to their nanometric sizes and biocompatibility of chitosan. Chitosan-Titanium dioxide (CS-TiO2) nanocomposite was synthesized and their optical, structural, spectral, thermal, morphological and elemental analyses were carried out by several techniques. The particle size of the synthesized CS-TiO2 nanocomposite was around 90 nm and has a crystalline structure with anatase phase of TiO2. The prepared nanocomposite acts as a photocatalyst for the removal of rhodamine B (RhB) and congo red (CR) dyes under visible light irradiation. The pseudo first order kinetics was derived according to Langmuir-Hinshelwood (L-H) model. The nanocomposite also proved to be an excellent antimicrobial agent against Gram-positive and Gram-negative bacteria; and also show activity against fungus. The antimicrobial activity of the CS-TiO2 nanocomposites exhibits a zone of inhibition ranged between 10.333 +/- 0.5773 and 25.667 +/- 1.5275 (mm). (C) 2017 Elsevier B.V. All rights reserved.
引用
收藏
页码:1762 / 1773
页数:12
相关论文
共 53 条
[1]   Photocatalytic activities of the nano-sized TiO2-supported Y-zeolites [J].
Anandan, S ;
Yoon, M .
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY C-PHOTOCHEMISTRY REVIEWS, 2003, 4 (01) :5-18
[2]   Chitin and chitosan in selected biomedical applications [J].
Anitha, A. ;
Sowmya, S. ;
Kumar, P. T. Sudheesh ;
Deepthi, S. ;
Chennazhi, K. P. ;
Ehrlich, H. ;
Tsurkan, M. ;
Jayakumar, R. .
PROGRESS IN POLYMER SCIENCE, 2014, 39 (09) :1644-1667
[3]   Physicochemical investigations of biogenic chitosan-silver nanocomposite as antimicrobial and anticancer agent [J].
Arjunan, Nithya ;
Kurnari, Henry Linda Jeeva ;
Singaravelu, Chandra Mohan ;
Kandasamy, Ruckmani ;
Kandasamy, Jothivenkatachalarn .
INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES, 2016, 92 :77-87
[4]   Double-doped TiO2 nanoparticles as an efficient visible-light-active photocatalyst and antibacterial agent under solar simulated light [J].
Ashkarran, Ali Akbar ;
Hamidinezhad, Habib ;
Haddadi, Hedayat ;
Mahmoudi, Morteza .
APPLIED SURFACE SCIENCE, 2014, 301 :338-345
[5]   Synthesis and characterization of zirconium-doped mesoporous nano-crystalline TiO2 [J].
Bineesh, Kanattukara Vijayan ;
Kim, Dong-Kyu ;
Park, Dae-Won .
NANOSCALE, 2010, 2 (07) :1222-1228
[6]   Graphene oxide coupled with gold nanoparticles for localized surface plasmon resonance based gas sensor [J].
Cittadini, Michela ;
Bersani, Marco ;
Perrozzi, Francesco ;
Ottaviano, Luca ;
Wlodarski, Wojtek ;
Martucci, Alessandro .
CARBON, 2014, 69 :452-459
[7]   Photoassisted bleaching of dyes utilizing TiO2 and visible light [J].
Epling, GA ;
Lin, C .
CHEMOSPHERE, 2002, 46 (04) :561-570
[8]   TiO2/CeO2 Hybrid Photocatalyst with Enhanced Photocatalytic Activity: Optimization of Synthesis Variables [J].
Eskandarloo, Hamed ;
Badiei, Alireza ;
Behnajady, Mohammad A. .
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2014, 53 (19) :7847-7855
[9]   Synergistic Effect of Chitosan and Titanium Dioxide on the Removal of Toxic Dyes by the Photodegradation Technique [J].
Farzana, M. Hasmath ;
Meenakshi, Sankaran .
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2014, 53 (01) :55-63
[10]   TiO2 photocatalysis and related surface phenomena [J].
Fujishima, Akira ;
Zhang, Xintong ;
Tryk, Donald A. .
SURFACE SCIENCE REPORTS, 2008, 63 (12) :515-582