Co3O4@graphene Composites as Anode Materials for High-Performance Lithium Ion Batteries

被引：347

作者：

Li, Baojun ^{[1
]}

Cao, Huaqiang ^{[1
]}

Shao, Jin ^{[2
]}

Li, Guoqiang ^{[2
]}

Qu, Meizhen ^{[2
]}

Yin, Gui ^{[3
]}

机构：

[1] Tsinghua Univ, Dept Chem, Beijing 100084, Peoples R China

[2] Chinese Acad Sci, Chengdu Inst Organ Chem, Chengdu 610041, Peoples R China

[3] Nanjing Univ, Dept Chem, Nanjing 210093, Peoples R China

来源：

INORGANIC CHEMISTRY | 2011年 / 50卷 / 05期

基金：

国家高技术研究发展计划(863计划); 中国国家自然科学基金;

关键词：

SN-C COMPOSITE; HIGH-CAPACITY; REVERSIBLE CAPACITY; CO3O4; NANOTUBES; HOLLOW; NANOPARTICLES; ELECTRODES; STABILITY; COBALT; SHEETS;

D O I：

10.1021/ic1023086

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

This paper reports on the synthesis of Co3O4@graphene composites (CGC) and their applications as anode materials in lithium ion batteries (LIBs). Through a chemical deposition method, Co3O4 nanoparticles (NPs) with sizes in the range of 10-30 nm were homogeneously dispersed onto graphene sheets. Due to their high electrical conductivity, the graphene sheets in the CGC improved the electrical conductivity and the structure stability of CGC. CGC displayed a superior performance in LIBs with a large reversible capacity value of 941 mA hg(-1) in the initial cycle with a large current density and an excellent cyclic performance of 740 mA hg(-1) after 60 cycles, corresponding to 88.3% of the theoretical value of CGC, owing to the interactions between graphene sheets and Co3O4 NPs anchored on the graphene sheets. This synthesis approach may find its application in the design and synthesis of novel electrode materials used in LIBs.

引用

页码：1628 / 1632

页数：5

共 41 条

[1] Building better batteries [J].

Armand, M. ;

Tarascon, J. -M. .

NATURE, 2008, 451 (7179) :652-657

[2] Microwave-assisted synthesis of a Co3O4-graphene sheet-on-sheet nanocomposite as a superior anode material for Li-ion batteries [J].

Chen, Shuang Qiang ;

Wang, Yong .

JOURNAL OF MATERIALS CHEMISTRY, 2010, 20 (43) :9735-9739

[3] Nanocomposite polymer electrolytes for lithium batteries [J].

Croce, F ;

Appetecchi, GB ;

Persi, L ;

Scrosati, B .

NATURE, 1998, 394 (6692) :456-458

[4] Nanostructured Sn-C composite as an advanced anode material in high-performance lithium-ion batteries [J].

Derrien, Gaelle ;

Hassoun, Jusef ;

Panero, Stefania ;

Scrosati, Bruno .

ADVANCED MATERIALS, 2007, 19 (17) :2336-+

[5]

Dong Z, 2007, J PHYS CHEM C, V111, P18475, DOI [10.1021/jp075365l, 10.1021/jp0753651]

[6] Porous Co3O4 nanotubes derived from Co4(CO)12 clusters on carbon nanotube templates:: A highly efficient material for Li-battery applications [J].

Du, Ning ;

Zhang, Hui ;

Chen, Bindi ;

Wu, Jianbo ;

Ma, Xiangyang ;

Liu, Zhihong ;

Zhang, Yiqiang ;

Yang, Deren ;

Huang, Xiaohua ;

Tu, Jiangping .

ADVANCED MATERIALS, 2007, 19 (24) :4505-+

[7] Deoxygenation of Exfoliated Graphite Oxide under Alkaline Conditions: A Green Route to Graphene Preparation [J].

Fan, Xiaobin ;

Peng, Wenchao ;

Li, Yang ;

Li, Xianyu ;

Wang, Shulan ;

Zhang, Guoliang ;

Zhang, Fengbao .

ADVANCED MATERIALS, 2008, 20 (23) :4490-4493

[8] Raman spectrum of graphene and graphene layers [J].

Ferrari, A. C. ;

Meyer, J. C. ;

Scardaci, V. ;

Casiraghi, C. ;

Lazzeri, M. ;

Mauri, F. ;

Piscanec, S. ;

Jiang, D. ;

Novoselov, K. S. ;

Roth, S. ;

Geim, A. K. .

PHYSICAL REVIEW LETTERS, 2006, 97 (18)

[9] Layered Graphene/Quantum Dots for Photovoltaic Devices [J].

Guo, Chun Xian ;

Yang, Hong Bin ;

Sheng, Zhao Min ;

Lu, Zhi Song ;

Song, Qun Liang ;

Li, Chang Ming .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2010, 49 (17) :3014-3017

[10] A nanostructured Sn-C composite lithium battery electrode with unique stability and high electrochemical performance [J].

Hassoun, Jusef ;

Derrien, Gaelle ;

Panero, Stefania ;

Scrosati, Bruno .

ADVANCED MATERIALS, 2008, 20 (16) :3169-3175

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