An Approach to Measure the Water Breakthrough in Porous Carbon Materials

被引:2
作者
Schwager, M. [1 ]
Dhanushkodi, S. R. [2 ]
Merida, W. [2 ]
机构
[1] Univ British Columbia, Dept Mech Engn, Vancouver, BC V6T 1Z4, Canada
[2] Univ British Columbia, Clean Energy Res Ctr, Vancouver, BC V6T 1Z4, Canada
关键词
MEMBRANE FUEL-CELLS; GAS-DIFFUSION LAYERS; LIQUID WATER; MICROPOROUS LAYER; PERFORMANCE LOSS; TRANSPORT; PEMFC; PRESSURE; VISUALIZATION; DURABILITY;
D O I
10.1149/2.0071504eel
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
We report a new characterization method that detects liquid water breakthrough in porous materials by measuring changes in relative humidity and electrochemical impedance simultaneously. Unlike previous work based on capillary pressure, a four-chamber tool was developed to monitor the pressure and dew point temperature across porous transport layer materials. This approach can characterize the structure and water transport behavior of carbonaceous materials for polymer electrolyte fuel cells and electrolyzers. The changes in the dew point, impedance, and pressure provide a reliable and fast indicator to predict the liquid water breakthrough. (C) 2015 The Electrochemical Society.
引用
收藏
页码:F32 / F34
页数:3
相关论文
共 22 条
[1]   Experimental investigation of the role of a microporous layer on the water transport and performance of a PEM fuel cell [J].
Atiyeh, Hasan K. ;
Karan, Kunal ;
Peppley, Brant ;
Phoenix, Aaron ;
Halliop, Ela ;
Pharoah, Jon .
JOURNAL OF POWER SOURCES, 2007, 170 (01) :111-121
[2]   Effect of compression on liquid water transport and microstructure of PEMFC gas diffusion layers [J].
Bazylak, A. ;
Sinton, D. ;
Liu, Z. -S. ;
Djilali, N. .
JOURNAL OF POWER SOURCES, 2007, 163 (02) :784-792
[3]   Dynamic water transport and droplet emergence in PEMFC gas diffusion layers [J].
Bazylak, Aimy ;
Sinton, David ;
Djilali, Ned .
JOURNAL OF POWER SOURCES, 2008, 176 (01) :240-246
[4]   Water flow in the gas diffusion layer of PEM fuel cells [J].
Benziger, J ;
Nehlsen, J ;
Blackwell, D ;
Brennan, T ;
Itescu, J .
JOURNAL OF MEMBRANE SCIENCE, 2005, 261 (1-2) :98-106
[5]   Determination of Liquid Water Distribution in Porous Transport Layers [J].
Buechi, Felix N. ;
Flueckiger, Reto ;
Tehlar, Denis ;
Marone, Federica ;
Stampanoni, Marco .
PROTON EXCHANGE MEMBRANE FUEL CELLS 8, PTS 1 AND 2, 2008, 16 (02) :587-+
[6]   Reactive sensor for investigation of gas diffusion layer hydrophobicity in PEM fuel cells [J].
Cheng, Derek ;
Ye, Siyu ;
Gyenge, Elod .
ELECTROCHEMICAL AND SOLID STATE LETTERS, 2008, 11 (08) :B148-B152
[7]   Polymer Electrolyte Membrane Fuel Cells: Characterization and Diagnostics [J].
Dhanushkodi, S. R. ;
Schwager, M. ;
Merida, W. .
POLYMER ELECTROLYTE FUEL CELLS 14, 2014, 64 (03) :547-557
[8]   PEMFC Durability: Spatially Resolved Pt Dissolution in a Single Cell [J].
Dhanushkodi, S. R. ;
Schwager, M. ;
Todd, D. ;
Merida, W. .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2014, 161 (14) :F1315-F1322
[9]   Use of mechanistic carbon corrosion model to predict performance loss in Polymer Electrolyte Membrane fuel cells [J].
Dhanushkodi, S. R. ;
Kundu, S. ;
Fowler, M. W. ;
Pritzker, M. D. .
JOURNAL OF POWER SOURCES, 2014, 267 :171-181
[10]   Carbon corrosion fingerprint development and de-convolution of performance loss according to degradation mechanism in PEM fuel cells [J].
Dhanushkodi, S. R. ;
Tam, M. ;
Kundu, S. ;
Fowler, M. W. ;
Pritzker, M. D. .
JOURNAL OF POWER SOURCES, 2013, 240 :114-121