Modeling the electrical behavior of an alkaline hydrogen peroxide generating flow-through electrochemical reactor

被引：6

作者：

Piela, P

Wrona, PK

机构：

[1] Ind Chem Res Inst, PL-01793 Warsaw, Poland

[2] Univ Warsaw, Dept Chem, PL-02093 Warsaw, Poland

来源：

JOURNAL OF PHYSICAL CHEMISTRY B | 2001年 / 105卷 / 07期

关键词：

D O I：

10.1021/jp0007989

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Two limiting-case simplified models of mass- and charge-transport phenomena in a flow-through electrochemical reactor were developed. It is postulated that the true experimental system's behavior falls in between. The models account for energy loss due to the ohmic drop, forced convection, diffusion, and migration. The calculation results were compared against experimental data.

引用

页码：1494 / 1502

页数：9

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