Miscibility and specific interactions in poly(β-hydroxybutyrate-co-β-hydroxyvalerate) and poly(P-vinylphenol) blends

被引：10
作者：
Xing, PX [1 ]
Dong, LS
Feng, ZL
Feng, HQ
机构：
[1] Chinese Acad Sci, Changchun Inst Appl Chem, Polymer Phys Lab, Changchun 130022, Peoples R China
[2] Chinese Acad Sci, Wuhan Inst Phys, Wuhan 430071, Peoples R China
来源：
EUROPEAN POLYMER JOURNAL | 1998年 / 34卷 / 08期
关键词：
D O I：
10.1016/S0014-3057(97)00198-5
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
The blends of poly(beta-hydroxybutyrate-co-beta-hydroxyvalerate) (P(HB-co-HV)/poly(p-vinylphenol)(PVPh) were investigated by differential scanning calorimetry (DSC), Fourier transform IR (FT-IR) spectroscopy and high-resolution solid-state C-13 NMR techniques. Single glass transition temperatures existing in the whole composition range indicates that these blends are miscible. The presence of hydrogen bonding between the hydroxyl of PVPh and carbonyl of P(HB-co-HV), shown by FT-IR spectra, is the origin of the miscibility. Furthermore, results obtained by high-resolution solid-state C-13 NMR give more information about the structure of the blends. (C) 1998 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码：1207 / 1211
页数：5
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