Synthesis and Crystal Structure of the Coordination Polymer [Cu(ppca′)2(H2O)(HgI2)](H2O) (ppca′ = 3,4′-bipyridine-6-carboxylic acid)

被引：2

作者：

Severance, Rachel C. ^{[1
]}

Ellsworth, Joe ^{[1
]}

Smith, Mark D. ^{[1
]}

Kelley, Jennifer ^{[2
]}

Peterson, LeRoy, Jr. ^{[2
]}

zur Loye, Hans-Conrad ^{[1
]}

机构：

[1] Univ S Carolina, Dept Chem & Biochem, Columbia, SC 29208 USA

[2] Francis Marion Univ, Dept Chem, Florence, SC 29502 USA

来源：

JOURNAL OF CHEMICAL CRYSTALLOGRAPHY | 2010年 / 40卷 / 12期

基金：

美国国家科学基金会;

关键词：

Coordination polymer; Copper (II); Mercury (II) iodide; Hydrothermal synthesis; 3,4 '-bipyridine-6-carboxylic acid; 4,4'-BIPYRIDINE-2-CARBOXYLIC ACID; METAL; FRAMEWORK; PYRAZINE-2-CARBOXYLATE; LIGAND;

D O I：

10.1007/s10870-010-9796-5

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The coordination polymer [Cu(ppca')(2)(H2O)(HgI2)](H2O) (1) was synthesized hydrothermally using the ligand 3,4'-bipyridine-6-carboxylic acid (ppca'). Structure 1 consists of square pyramidal copper (II) units linked by mercury (II) iodide into one-dimensional zigzag chains, which hydrogen bond into double chains. These ladders are further hydrogen bonded into a three-dimensional network that crystallizes in the monoclinic C2/c space group. In structure 1, a = 16.9058(10) angstrom, b = 11.2645(6) angstrom, c = 27.2707(15) angstrom, and beta = 92.754(1)degrees.

引用

页码：1069 / 1073

页数：5

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