Synthesis and Crystal Structure of the Coordination Polymer [Cu(ppca′)2(H2O)(HgI2)](H2O) (ppca′ = 3,4′-bipyridine-6-carboxylic acid)

被引：2
作者：
Severance, Rachel C. [1 ]
Ellsworth, Joe [1 ]
Smith, Mark D. [1 ]
Kelley, Jennifer [2 ]
Peterson, LeRoy, Jr. [2 ]
zur Loye, Hans-Conrad [1 ]
机构：
[1] Univ S Carolina, Dept Chem & Biochem, Columbia, SC 29208 USA
[2] Francis Marion Univ, Dept Chem, Florence, SC 29502 USA
来源：
JOURNAL OF CHEMICAL CRYSTALLOGRAPHY | 2010年 / 40卷 / 12期
基金：
美国国家科学基金会;
关键词：
Coordination polymer; Copper (II); Mercury (II) iodide; Hydrothermal synthesis; 3,4 '-bipyridine-6-carboxylic acid; 4,4'-BIPYRIDINE-2-CARBOXYLIC ACID; METAL; FRAMEWORK; PYRAZINE-2-CARBOXYLATE; LIGAND;
D O I：
10.1007/s10870-010-9796-5
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The coordination polymer [Cu(ppca')(2)(H2O)(HgI2)](H2O) (1) was synthesized hydrothermally using the ligand 3,4'-bipyridine-6-carboxylic acid (ppca'). Structure 1 consists of square pyramidal copper (II) units linked by mercury (II) iodide into one-dimensional zigzag chains, which hydrogen bond into double chains. These ladders are further hydrogen bonded into a three-dimensional network that crystallizes in the monoclinic C2/c space group. In structure 1, a = 16.9058(10) angstrom, b = 11.2645(6) angstrom, c = 27.2707(15) angstrom, and beta = 92.754(1)degrees.
引用
收藏
页码：1069 / 1073
页数：5
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