Preparation and characterization of new self-setting calcium phosphate cements based on alkali containing orthophosphates

被引:2
作者
Berger, G [1 ]
Gildenhaar, R [1 ]
Pauli, J [1 ]
Marx, H [1 ]
机构
[1] Fed Inst Mat Res & Testing, D-12200 Berlin, Germany
来源
BIOCERAMICS, VOL 17 | 2005年 / 284-286卷
关键词
P-31-NMR investigation; Ca2KNa(PO4)(2); calcium alkali orthophosphates; calcium phosphate cement; self-setting cement;
D O I
10.4028/www.scientific.net/KEM.284-286.121
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
This paper deals with calcium phosphate cements containing alkali to achieve higher solubility. Until now normally for all cements also if alkali was integrated the self-setting process leads to hydroxyapatite (HA) or calcium deficient HA (CDHA). In cases where fluid dispersions of HA were used for bone defect treatment the HA remains and do not acts self-hardening. The self-setting cements show high compressive strength in comparison to the HA supplied as a paste. They show latent hydraulic behavior during the self-hardening process. The following storage in SBF for four weeks also did not lead to a strong change of the starting materials that were Ca2KNa(PO4)(2) or Ca-10[K/Na](PO4)(7).
引用
收藏
页码:121 / 124
页数:4
相关论文
共 9 条
[1]  
Brown W.E., 1985, U.S. Patent, Patent No. [No. 4518430, 4518430]
[2]   Development of a new calcium phosphate cement that contains sodium calcium phosphate [J].
Doi, Y ;
Shimizu, Y ;
Moriwaki, Y ;
Aga, M ;
Iwanaga, H ;
Shibutani, T ;
Yamamoto, K ;
Iwayama, Y .
BIOMATERIALS, 2001, 22 (08) :847-854
[3]   The Ca/P range of nanoapatitic calcium phosphate cements [J].
Driessens, FCM ;
Boltong, MG ;
de Maeyer, EAP ;
Wenz, R ;
Nies, B ;
Planell, JA .
BIOMATERIALS, 2002, 23 (19) :4011-4017
[4]  
DRIESSENS FCM, 1996, BIOCERAMICS, V9
[5]  
DRIESSENS FCM, BIOMINERALS
[6]   Production and characterization of new calcium phosphate bone cements in the CaHPO4-α-Ca3(PO4)2 system:: pH, workability and setting times [J].
Fernández, E ;
Gil, FJ ;
Ginebra, MP ;
Driessens, FCM ;
Planell, JA ;
Best, SM .
JOURNAL OF MATERIALS SCIENCE-MATERIALS IN MEDICINE, 1999, 10 (04) :223-230
[7]  
Gross V, 2002, KEY ENG MAT, V218-2, P307
[8]   A thorough physicochemical characterisation of 14 calcium phosphate-based bone substitution materials in comparison to natural bone [J].
Tadic, D ;
Epple, M .
BIOMATERIALS, 2004, 25 (06) :987-994
[9]  
Van Wazer JR., 1961, PHOSPHORUS ITS COMPO