Triazolyl-Based Molecular Gels as Ligands for Autocatalytic 'Click' Reactions

被引：23

作者：

Araujo, Marco ^{[1
]}

Diaz-Oltra, Santiago ^{[1
]}

Escuder, Beatriu ^{[1
]}

机构：

[1] Univ Jaume 1, Dept Quim Inorgan & Organ, Castellon de La Plana 12071, Spain

来源：

CHEMISTRY-A EUROPEAN JOURNAL | 2016年 / 22卷 / 25期

关键词：

click chemistry; gels; heterogeneous catalysis; self-assembly; supramolecular chemistry; CYCLOADDITION; CHEMISTRY; COPPER(I); CATALYSTS;

D O I：

10.1002/chem.201600594

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The catalytic performance of triazolyl-based molecular gels was investigated in the Huisgen 1,3-dipolar cycloaddition of alkynes and azides. Low-molecular-weight gelators derived from l-valine were synthesized and functionalized with a triazole fragment. The resultant compounds formed gels either with or without copper, in a variety of solvents of different polarity. The gelators coordinated Cu-I and exhibited a high catalytic activity in the gel phase for the model reaction between phenylacetylene and benzylazide. Additionally, the gels were able to participate in autocatalytic synthesis and the influence of small structural changes on their performance was observed.

引用

页码：8676 / 8684

页数：9

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