A polymer surface treatment irradiated system by XeCl excimer laser is designed, bond strengths are measured by shear test method. The bond strengths of fluorocarbon-resin with aluminous bar is improved by solutions such as water (H2O), boric acid (H3BO3), sodium hydroxide (NaOH), bluestone (CuSO4), sodium aluminate (NaAlO2) reacting with fluorocarbon-resin while XeCl excimer laser irradiating. The relationship between the adhesion force with the laser intensity and laser pulse shots are measured. The mechanism of these phenomena is discussed.