Effect of the incorporation of interfacial elements on the thermophysical properties of Cu/VGCNFs composites

被引:10
作者
Barcena, J. [1 ]
Garcia de Cortazar, M. [1 ]
Seddon, R. [1 ]
Lloyd, J. C. [2 ]
Torregaray, A. [3 ]
Coleto, J. [1 ]
机构
[1] INASMET Tecnalia, Funct Mat & Particle Technol Dept, E-20009 Donostia San Sebastian, Spain
[2] Univ Cambridge, Gordon Lab, Cambridge CB2 3QZ, England
[3] Univ Basque Country EHU, EUITI IITUE, Dept Ingn Minera Met & Ciencia Mat, E-48012 Bilbao, Spain
关键词
Vapour grown carbon nanofibres; Metal-matrix composites (MMCs); Nano composites; Interface; Thermal properties; CARBON-NANOTUBE; COPPER;
D O I
10.1016/j.compscitech.2010.05.025
中图分类号
TB33 [复合材料];
学科分类号
摘要
Vapour grown carbon nanofibres exhibit high mechanical properties and thermal conductivities. Therefore they are potential reinforcements in composites materials for high strength and high thermal conductivity applications. A problem not yet solved is the promotion of an improved copper/carbon interface. Several strategies have been envisaged for the incorporation of alloying elements (Ni, Co, B and Ti) at the interface. These techniques are based on duplex electroless plating coatings (combination of Cu and Ni or Cu and Co), electroless plating of alloys (Cu-B) and addition of metal nanoparticles (Ti) to Cu matrix deposited by electroless plating. The effect of the incorporation of these metallic elements on the microstructure and thermophysical properties is discussed. B and Ti lead to higher interaction at the Cu/C interface over Ni and Co. This allows the reduction of the coefficient of thermal expansion but regarding the thermal conductivity it was not possible to obtain a value higher than that of copper. (C) 2010 Elsevier Ltd. All rights reserved.
引用
收藏
页码:2258 / 2262
页数:5
相关论文
共 14 条
[1]   Nickel-coated carbon nanofibers prepared by electroless deposition [J].
Arai, S ;
Endo, M ;
Hashizume, S ;
Shimojima, Y .
ELECTROCHEMISTRY COMMUNICATIONS, 2004, 6 (10) :1029-1031
[2]  
BARCENA J, 2008, P 10 C NAC MAT DON S
[3]   Microstructural study of vapour grown carbon nanofibre/copper composites [J].
Barcena, Jorge ;
MaudeSa, Jon ;
Coletoa, Javier ;
Baldonedo, Juan L. ;
de Salazar, Jose M. Gomez .
COMPOSITES SCIENCE AND TECHNOLOGY, 2008, 68 (06) :1384-1391
[4]   Microstructure of Cu-C interface in Cu-based metal matrix composite [J].
Berner, A ;
Mundim, KC ;
Ellis, DE ;
Dorfman, S ;
Fuks, D ;
Evenhaim, R .
SENSORS AND ACTUATORS A-PHYSICAL, 1999, 74 (1-3) :86-90
[5]   Carbon-nanotube metal-matrix composites prepared by electroless plating [J].
Chen, XH ;
Xia, JT ;
Peng, JC ;
Li, WZ ;
Xie, SS .
COMPOSITES SCIENCE AND TECHNOLOGY, 2000, 60 (02) :301-306
[6]   Growth and characterization of electroless deposited Cu films on carbon nanofibers [J].
Cordoba, J. M. ;
Oden, M. .
SURFACE & COATINGS TECHNOLOGY, 2009, 203 (22) :3459-3464
[7]   Preparation of CNFs surface to coat with copper by electroless process [J].
de Salazar, J. M. Gomez ;
Barrena, M. I. ;
Merino, C. ;
Merino, N. .
MATERIALS LETTERS, 2008, 62 (03) :494-497
[8]   Introduction to carbon nanotube and nanofiber smart materials [J].
Kang, Inpil ;
Heung, Yun Yeo ;
Kim, Jay H. ;
Lee, Jong Won ;
Gollapudi, Ramanand ;
Subramaniam, Srinivas ;
Narasimhadevara, Suhasini ;
Hurd, Douglas ;
Kirikera, Goutham R. ;
Shanov, Vesselin ;
Schulz, Mark J. ;
Shi, Donglu ;
Boerio, Jim ;
Mall, Shankar ;
Ruggles-Wren, Marina .
COMPOSITES PART B-ENGINEERING, 2006, 37 (06) :382-394
[9]   The solubility of C in solid Cu [J].
López, GA ;
Mittemeijer, E .
SCRIPTA MATERIALIA, 2004, 51 (01) :1-5
[10]  
MILLER RG, 1978, Patent No. 4082898