Statistical field theory for simple fluids: mean field and Gaussian approximations

被引:27
作者
Caillol, JM [1 ]
机构
[1] Univ Paris 11, LPT, CNRS, UMR 8627, F-91405 Orsay, France
关键词
D O I
10.1080/0026897031000068488
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
We present an exact field theoretical representation of the statistical mechanics of simple classical liquids with short-range pairwise additive interactions. The action of the field theory is obtained by performing a Hubbard-Stratonovich transformation of the configurational Boltzmann factor. The mean field and Gaussian approximations of the theory are derived and applications to the liquid-vapour transition considered.
引用
收藏
页码:1617 / 1634
页数:18
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