Epitaxial stabilization of SmNiO3 films on (001) SrTiO3 substrates

被引:14
作者
Conchon, F.
Boulle, A.
Girardot, C.
Pignard, S.
Guinebretiere, R.
Dooryhee, E.
Hodeau, J-L
Weiss, F.
Kreisel, J.
Berar, J-F
机构
[1] ENSCI, Lab Sci Procedes Ceram & Traitements Surfaces SPC, CNRS, UMR 6638, F-87065 Limoges, France
[2] INP Grenoble, MINATEC, LMGP, CNRS UMR 5628, F-38016 Grenoble, France
[3] CNRS, UPR 2940, Inst Neel IN, F-38042 Grenoble, France
关键词
D O I
10.1088/0022-3727/40/16/017
中图分类号
O59 [应用物理学];
学科分类号
摘要
The epitaxial stabilization of SmNiO3 (SNO) films grown by an injection MO-CVD process on ( 0 0 1) SrTiO3 (STO) substrates is discussed. By means of high-resolution x-ray diffraction, we show for the first time that SNO can be stabilized on STO with a minor amount of secondary phases and with a layer thickness reaching several hundreds of nanometres. It is argued that this stabilization is achieved because the lattice mismatch between these two perovskites is not as high as expected (1.8% instead of 2.8%). Moreover, the well-known dissociation of the SNO phase into NiO and Sm2O3 has been clearly correlated with the relaxation of epitaxial strain which is driven by the formation of misfit dislocations.
引用
收藏
页码:4872 / 4876
页数:5
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