Integration of aggregation-induced emission and delayed fluorescence into electronic donor-acceptor conjugates

被引:108
作者
Gan, Shifeng [1 ]
Luo, Wenwen [1 ]
He, Bairong [1 ]
Chen, Long [1 ]
Nie, Han [1 ]
Hu, Rongrong [1 ]
Qin, Anjun [1 ]
Zhao, Zujin [1 ]
Tang, Ben Zhong [1 ,2 ,3 ]
机构
[1] S China Univ Technol, State Key Lab Luminescent Mat & Devices, Guangzhou 510640, Guangdong, Peoples R China
[2] Hong Kong Univ Sci & Technol, Dept Chem, Kowloon, Hong Kong, Peoples R China
[3] Chinese Natl Engn Res Ctr Tissue Restorat & Recon, Hong Kong Branch, Hong Kong, Hong Kong, Peoples R China
基金
中国国家自然科学基金;
关键词
LIGHT-EMITTING-DIODES; ROOM-TEMPERATURE PHOSPHORESCENCE; INTERNAL QUANTUM EFFICIENCY; DESIGN; DERIVATIVES; COMPOUND;
D O I
10.1039/c5tc03588k
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
A series of luminogens comprised electron donors and acceptors are found to possess two types of interesting photophysical processes of aggregation-induced emission (AIE) and delayed fluorescence. According to theory calculation, restriction of intramolecular motions accounts for their AIE characteristics. Moreover, a separated distribution of the HOMOs and the LUMOs of these luminogens leads to small DEST values and therefore delayed fluorescence.
引用
收藏
页码:3705 / 3708
页数:4
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