Sono-RAFT Polymerization in Aqueous Medium

被引：139

作者：

McKenzie, Thomas G. ^{[1
]}

Colombo, Enrico ^{[2
]}

Fu, Qiang ^{[1
]}

Ashokkumar, Muthupandian ^{[2
]}

Qiao, Greg G. ^{[1
]}

机构：

[1] Univ Melbourne, Polymer Sci Grp, Dept Chem & Biomol Engn, Melbourne, Vic 3010, Australia

[2] Univ Melbourne, Sonochem Res Team, Sch Chem, Melbourne, Vic 3010, Australia

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2017年 / 56卷 / 40期

基金：

澳大利亚研究理事会;

关键词：

controlled polymerization; hydroxyl radicals; RAFT polymerization; sonochemistry; LIVING RADICAL POLYMERIZATION; FRAGMENTATION CHAIN-TRANSFER; ULTRASONIC IRRADIATION; HIGH-FREQUENCY; VISIBLE-LIGHT; METHACRYLATE; CHEMISTRY; INIFERTER; MONOMERS; STYRENE;

D O I：

10.1002/anie.201706771

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The ultrasonic irradiation of aqueous solution is demonstrated to be a suitable source of initiating radicals for a controlled radical polymerization when conducted in the presence of a thiocarbonylthio-containing reversible addition-fragmentation chain transfer (RAFT) agent. This allows for a highly green method of externally regulated/controlled polymerization with a potentially broad scope for polymerizable monomers and/or polymer structures.

引用

页码：12302 / 12306

页数：5

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