Metallosalen-based crystalline porous materials: Synthesis and property

被引：81
|
作者：
Yuan, Guozan [1 ]
Jiang, Hong [1 ,2 ,3 ]
Zhang, Liyan [1 ]
Liu, Yan [2 ,3 ]
Cui, Yong [2 ,3 ]
机构：
[1] Anhui Univ Technol, Sch Chem & Chem Engn, Maanshan 243032, Peoples R China
[2] Shanghai Jiao Tong Univ, Sch Chem & Chem Engn, Shanghai 200240, Peoples R China
[3] Shanghai Jiao Tong Univ, State Key Lab Met Matrix Composites, Shanghai 200240, Peoples R China
来源：
COORDINATION CHEMISTRY REVIEWS | 2019年 / 378卷
基金：
美国国家科学基金会;
关键词：
Metallosalen; Metal-organic frameworks; Metallacycles; Covalent organic frameworks; Catalysis and molecule separation; Sensing; METAL-ORGANIC FRAMEWORKS; SELF-ASSEMBLED METALLACYCLES; SCHIFF-BASE; ENANTIOSELECTIVE RECOGNITION; PHOTOCATALYTIC DEGRADATION; ASYMMETRIC CYANOSILYLATION; HETEROGENEOUS CATALYSTS; RATIONAL DESIGN; SALEN; COMPLEXES;
D O I：
10.1016/j.ccr.2017.10.032
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Salen-type ligands have been used extensively to stabilize metals for homogeneous catalysis. It has been demonstrated that the marriage of complexes of salen with porous materials is a promising way to combine the attractive properties of the salen complexes with those of the porous structures. In this review, we summarize the recent research progress in metallosalen-based crystalline porous materials (CPMs), including metal-organic frameworks, coordination metallacycles, and covalent organic frameworks. Emphasis is placed on the syntheses, and structures of these porous materials, and their properties of catalysis, molecule separation, sensing and magnetic resonance imaging. (C) 2017 Elsevier B.V. All rights reserved.
引用
收藏
页码：483 / 499
页数：17
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