Synthesis and magnetic property of vanadium garnets AgCa2Cu2V3O12 and AgCa2Zn2V3O12

被引：8

作者：

Awaka, J ^{[1
]}

Katagi, R ^{[1
]}

Sasaki, H ^{[1
]}

Endoh, R ^{[1
]}

Matsumoto, N ^{[1
]}

Ebisu, S ^{[1
]}

Nagata, S ^{[1
]}

机构：

[1] Muroran Inst Technol, Dept Mat Sci & Engn, Muroran, Hokkaido 0508585, Japan

来源：

JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS | 2001年 / 62卷 / 04期

关键词：

inorganic compounds; oxides; chemical synthesis; magnetic properties;

D O I：

10.1016/S0022-3697(00)00234-1

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Vanadium garnets AgCa2Cu2V3O12 and AgCa2Zn2V3O12 have been successfully synthesized. The X-ray diffraction experiments indicate that these compounds have the garnet structure of cubic symmetry of space group Ia(3) over bard (O-h(10)) with the lattice constant of 12.465 Angstrom (AgCa2Cu2V3O12) and 12.491 Angstrom (AgCa2Zn2V3O12), respectively. The magnetic susceptibility of AgCa2Cu2V3O12 has the Curie-Weiss paramagnetic behavior with the effective magnetic moment of 1.97 mu (B) due to Cu2+ ion at A-site and the Weiss constant of -10.1 K (antiferromagnetic sign). On the other hand, AgCa2Zn2V3O12 exhibits a fairly perfect non-magnetic state of all the cations with the closed shell. (C) 2001 Elsevier Science Ltd. All rights reserved.

引用

页码：743 / 746

页数：4