[WS4Cu3I2]- and [WS4Cu4]2+ secondary building units formed a metal-organic framework: Large tubes in a highly interpenetrated system

被引：72

作者：

Lu, Zhen-Zhong ^{[1
]}

Zhang, Rui ^{[1
]}

Li, Yi-Zhi ^{[1
]}

Guo, Zi-Jian ^{[1
]}

Zheng, He-Gen ^{[1
]}

机构：

[1] Nanjing Univ, State Key Lab Coordinat Chem, Sch Chem & Chem Engn, Natl Lab Microstruct, Nanjing 210093, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2011年 / 47卷 / 10期

关键词：

CRYSTAL-STRUCTURE; CLUSTER; NETS; CHEMISTRY; POLYMERS; DESIGN;

D O I：

10.1039/c0cc05015f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A 3D metal-organic framework, {[WS4Cu4(dpbp)(4)](2+)center dot[WS4Cu3(dpbp)(2)I-2](-)center dot I-}(n)center dot xSolvent, [dpbp = 4,4'-di(4-pyridyl)-biphenyl] with an unprecedent 8-fold non-equivalent interpenetration mode is presented, which contains four anionic and four cationic frameworks formed by tetranuclear [WS4Cu3I2](-) and pentanuclear [WS4Cu4](2+) SBUs with long dpbp ligands. Large rhombus-shaped tubes with diagonal dimensions of similar to 20 x 10 angstrom are formed in spite of high interpenetration.

引用

页码：2919 / 2921

页数：3

共 50 条

[21] A double-walled triangular metal-organic macrocycle based on a [Cu2(COO)4] square paddle-wheel secondary building unit
Song, Xiaokai
Liu, Xinfang
Oh, Minhak
Lah, Myoung Soo
DALTON TRANSACTIONS, 2010, 39 (27) : 6178 - 6180
[22] Formation of a mixed-valence Cu(i)/Cu(ii) metal-organic framework with the full light spectrum and high selectivity of CO2 photoreduction into CH4
Gao, Yajun
Zhang, Lei
Gu, Yuming
Zhang, Wenwei
Pan, Yi
Fang, Weihai
Ma, Jing
Lan, Ya-Qian
Bai, Junfeng
CHEMICAL SCIENCE, 2020, 11 (37) : 10143 - 10148
[23] A Metal-organic Framework with Paddle-wheel Zn2(CO2)4 Secondary Building Units and Cubane-1,4-dicarboxylic Acid Linkers
Foldes, David
Kovats, Eva
Bortel, Gabor
Jakab, Emma
Pekker, Sandor
PERIODICA POLYTECHNICA-CHEMICAL ENGINEERING, 2019, 63 (03) : 365 - 369
[24] New Coordination Polymers and Porous Supramolecular Metal Organic Network Based on the Trinuclear Triangular Secondary Building Unit [Cu3(μ3-0H)(μ-pz)3]2+ and 4,4′-Bypiridine. 1°
Di Nicola, Corrado
Garau, Federica
Gazzano, Massimo
Guedes da Silva, M. Fatima C.
Lanza, Arianna
Monari, Magda
Nestola, Fabrizio
Pandolfo, Luciano
Pettinari, Claudio
Pombeiro, Armando J. L.
CRYSTAL GROWTH & DESIGN, 2012, 12 (06) : 2890 - 2901
[25] An unusual (4,10)-connected 3-D metal-organic framework based on non-planar tricarboxyl tecton and tetracadmium(II) secondary building units
Fang, Shao-Ming
Chen, Min
Yang, Xiao-Gang
Wang, Cong
Du, Miao
Liu, Chun-Sen
CRYSTENGCOMM, 2012, 14 (16): : 5299 - 5304
[26] Tailoring Coordination Microenvironment of Cu(I) in Metal-Organic Frameworks for Enhancing Electroreduction of CO2 to CH4
Zhang, Ya
Zhou, Qiang
Qiu, Zhao-Feng
Zhang, Xiao-Yu
Chen, Jia-Qi
Zhao, Yue
Gong, Feng
Sun, Wei-Yin
ADVANCED FUNCTIONAL MATERIALS, 2022, 32 (36)
[27] Two new 3-D photoluminescence metal-organic frameworks based on cubane Cu4I4 clusters as tetrahedral nodes
Hou, Qin
Jia, Ming-Jun
Zhao, Jin-Jing
Jin, Juan
Yu, Jie-Hui
Xu, Ji-Qing
INORGANICA CHIMICA ACTA, 2012, 384 : 287 - 292
[28] Doubly Interpenetrated Zn4O-Based Metal-Organic Framework for CO2 Chemical Transformation and Antibiotic Sensing
He, Hongming
Zhu, Qian-Qian
Guo, Mei-Tong
Zhou, Qiao-Shu
Chen, Jing
Li, Cheng-Peng
Du, Miao
CRYSTAL GROWTH & DESIGN, 2019, 19 (09) : 5228 - 5236
[29] Six [Tp☆WS3Cu2]-based clusters derived from [Et4N][Tp☆WS3], Cu(I) salts and phosphine ligands: syntheses, structures and enhanced third-order NLO properties
Zhou, Li-Kuan
Liu, Quan
Zhao, Xin
Hu, Fei-Long
Liu, Shu-Chen
Ren, Zhi-Gang
Sun, Zhen-Rong
Lang, Jian-Ping
DALTON TRANSACTIONS, 2014, 43 (12) : 4734 - 4744
[30] A Systematic Approach to Building Highly Porous, Noninterpenetrating Metal-Organic Frameworks with a Large Capacity for Adsorbing H2 and CH4
Lee, Jeong Yong
Pan, Long
Huang, Xiaoying
Emge, Thomas J.
Li, Jing
ADVANCED FUNCTIONAL MATERIALS, 2011, 21 (05) : 993 - 998

← 1 2 3 4 5 →