[WS4Cu3I2]- and [WS4Cu4]2+ secondary building units formed a metal-organic framework: Large tubes in a highly interpenetrated system

被引：72
|
作者：
Lu, Zhen-Zhong [1 ]
Zhang, Rui [1 ]
Li, Yi-Zhi [1 ]
Guo, Zi-Jian [1 ]
Zheng, He-Gen [1 ]
机构：
[1] Nanjing Univ, State Key Lab Coordinat Chem, Sch Chem & Chem Engn, Natl Lab Microstruct, Nanjing 210093, Peoples R China
来源：
CHEMICAL COMMUNICATIONS | 2011年 / 47卷 / 10期
关键词：
CRYSTAL-STRUCTURE; CLUSTER; NETS; CHEMISTRY; POLYMERS; DESIGN;
D O I：
10.1039/c0cc05015f
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A 3D metal-organic framework, {[WS4Cu4(dpbp)(4)](2+)center dot[WS4Cu3(dpbp)(2)I-2](-)center dot I-}(n)center dot xSolvent, [dpbp = 4,4'-di(4-pyridyl)-biphenyl] with an unprecedent 8-fold non-equivalent interpenetration mode is presented, which contains four anionic and four cationic frameworks formed by tetranuclear [WS4Cu3I2](-) and pentanuclear [WS4Cu4](2+) SBUs with long dpbp ligands. Large rhombus-shaped tubes with diagonal dimensions of similar to 20 x 10 angstrom are formed in spite of high interpenetration.
引用
收藏
页码：2919 / 2921
页数：3
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