Determination of Antimony(III) and Total Antimony in Aqueous Samples by Electrothermal Atomic Absorption Spectrometry After Dispersive Liquid-Liquid Microextraction (DLLME)

被引：28
作者：
Yousefi, S. R. [1 ]
Shemirani, F. [1 ]
Jamali, M. R. [2 ]
机构：
[1] Univ Tehran, Univ Coll Sci, Sch Chem, Tehran, Iran
[2] Payam Noor Univ, Dept Chem, Behshahr, Iran
来源：
ANALYTICAL LETTERS | 2010年 / 43卷 / 16期
关键词：
Dispersive liquid-liquid microextraction; Electrothermal atomic absorption spectrometry; Preconcentration; Speciation of antimony; EMISSION-SPECTROMETRY; SPECIATION ANALYSIS; ORGANIC-COMPOUNDS; WATER; EXTRACTION; SB(V); SB(III);
D O I：
10.1080/00032711003731381
中图分类号：
O65 [分析化学];
学科分类号：
070302 ; 081704 ;
摘要：
Dispersive liquid-liquid microextraction (DLLME) technique combined with electrothermal atomic absorption spectrometry (ET-AAS) was proposed for determination of antimony(III) and total antimony at very low concentrations in water samples. The N-benzoyl-N-phenylhydroxylamine (BPHA) was used as a chelating agent, and chloroform and ethanol were used as extraction and disperser solvents, respectively. The effect of various experimental parameters on the extraction and determination was investigated. The detection limits (3 sigma) were 0.005gL-1 for Sb(III) and 0.008gL-1 for total Sb. The developed method was applied successfully to the determination of Sb(III) and total Sb in natural water samples.
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页码：2563 / 2571
页数：9
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