Electric-field-induced charge transfer between gold nanoparticle and capping 2-naphthalenethiol and organic memory cells

被引:129
作者
Ouyang, JY [1 ]
Chu, CW [1 ]
Sieves, D [1 ]
Yang, Y [1 ]
机构
[1] Univ Calif Los Angeles, Dept Mat Sci & Engn, Los Angeles, CA 90095 USA
关键词
D O I
10.1063/1.1887819
中图分类号
O59 [应用物理学];
学科分类号
摘要
An electrical transition, induced by a high electric field, was observed in a device consisting of a polystyrene film containing 2-naphthalenethiol-capped Au nanoparticles sandwiched between two Al electrodes. The current through the device changed from a charge-injection-controlled current to a space-charge-limited current. The latter current is higher than the former by more than three orders of magnitude at 2 V. Asymmetrical current-voltage curve was observed along the two polarity directions for the device after the transition. This transition is attributed to an electric-field-induced charge transfer between the Au nanoparticle and the capping 2-naphthalenethiol. The device exhibits good stability in the high conductivity state, so it can be used as a write-once-read-many times electronic memory. (C) 2005 American Institute of Physics.
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页码:1 / 3
页数:3
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