Two Si-Si double bonds connected by a phenylene bridge

被引：89
作者：
Bejan, Iulia [1 ]
Scheschkewitz, David [1 ]
机构：
[1] Univ Wurzburg, Inst Anorgan Chem, D-97074 Wurzburg, Germany
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2007年 / 46卷 / 30期
关键词：
conjugation; disilene; double bonds; Group; 14; elements; silicon;
D O I：
10.1002/anie.200701744
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
(Chemical Equation Presented) Electronic communication between two Si-Si double bonds is enabled by a phenylene linkage and expressed in a large red shift of the longest-wavelength UV/Vis absorptions of deep red tetrasiladiene 1 compared to yellow phenyldisilene 2. © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码：5783 / 5786
页数：4
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