Site-selective fabrication of two-dimensional fullerene arrays by using a supramolecular template at the liquid-solid interface

被引：128
|
作者：
Li, Min [2 ]
Deng, Ke [1 ]
Lei, Sheng-Bin [1 ]
Yang, Yan-Lian [1 ]
Wang, Tai-Shan [2 ]
Shen, Yong-Tao [1 ]
Wang, Chun-Ru [2 ]
Zeng, Qing-Dao [1 ]
Wang, Chen [1 ]
机构：
[1] Natl Ctr Nanosci & Technol, Beijing 100080, Peoples R China
[2] Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2008年 / 47卷 / 35期
基金：
中国国家自然科学基金;
关键词：
azobenzenes; fullerenes; scanning probe microscopy; self-assembly; site selectivity;
D O I：
10.1002/anie.200802518
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
(Figure Presented) A selective invitation: A 2D hydrogen-bonded porous network formed by an azobenzene derivative (NN4A) contains two different types of cavities and is shown to selectively accommodate fullerenes C80 and Sc3N@C80 (see picture). Highly ordered fullerene arrays are constructed at the liquid-solid interface of graphite by coadsorption of fullerenes and NN4A. While C60 occupies both types of cavity, C80 and Sc3N@C80 are only immobilized in one cavity type. © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码：6717 / 6721
页数：5
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