Photocatalytic degradation of acridine dyes using anatase and rutile TiO2

被引：25
作者：
Zubieta, C. E. [1 ]
Messina, P. V. [2 ,3 ]
Schulz, P. C. [2 ,3 ]
机构：
[1] Univ Nacl Sur, IFISUR, RA-8000 Bahia Blanca, Buenos Aires, Argentina
[2] Univ Nacl Sur, Dept Quim, RA-8000 Bahia Blanca, Buenos Aires, Argentina
[3] Consejo Nacl Invest Cient & Tecn, INQUISUR, Bahia Blanca, Buenos Aires, Argentina
来源：
JOURNAL OF ENVIRONMENTAL MANAGEMENT | 2012年 / 101卷
关键词：
Titania; Microemulsion; Photodegradation; Pollution; Acridine dyes; Adsorption;
D O I：
10.1016/j.jenvman.2012.02.014
中图分类号：
X [环境科学、安全科学];
学科分类号：
08 ; 0830 ;
摘要：
The adsorption and photodegradation of acridine orange (AO) and acriflavine (AF) dyes on two mesoporous titania crystalline phases, anatase and rutile, were experimentally studied. Anatase and rutile were characterized by nitrogen adsorption, electron scanning and transmission microscopy, and X-ray diffraction. The adsorption capacity of rutile was higher than that of anatase, while the reverse is observed for photodegradation of both dyes. The adsorption of AF on both adsorbents was higher than that of AO, which was related with the smaller size of AF molecules compared with those of AO, therefore the access of AF to the adsorption sites is favored. (c) 2012 Published by Elsevier Ltd.
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页码：1 / 6
页数：6
相关论文
共 29 条
  • [1] Adamson A.W., 1997, PHYS CHEM SURFACES, P336
  • [2] Adamson A.W., 1998, PHYS CHEM SURFACES, P393
  • [3] Inorganic gels as precursors of TiO2 photocatalysts prepared by low temperature microwave or thermal treatment
    Addamo, Maurizio
    Bellardita, Marianna
    Carriazo, Daniel
    Di Paola, Agatino
    Milioto, Stefania
    Palmisano, Leonardo
    Rives, Vicente
    [J]. APPLIED CATALYSIS B-ENVIRONMENTAL, 2008, 84 (3-4) : 742 - 748
  • [4] IR-analysis of H-bonded H2O on the pure TiO2 surface
    Bezrodna, T
    Puchkovska, G
    Shymanovska, V
    Baran, J
    Ratajczak, H
    [J]. JOURNAL OF MOLECULAR STRUCTURE, 2004, 700 (1-3) : 175 - 181
  • [5] UV light induced photodegradation of malachite green on TiO2 nanoparticles
    Chen, C. C.
    Lu, C. S.
    Chung, Y. C.
    Jan, J. L.
    [J]. JOURNAL OF HAZARDOUS MATERIALS, 2007, 141 (03) : 520 - 528
  • [6] SELECTIVE CATALYTIC REDUCTION OF NO WITH NH3 ON SO4(-2)/TIO2 SUPERACID CATALYST
    CHEN, JP
    YANG, RT
    [J]. JOURNAL OF CATALYSIS, 1993, 139 (01) : 277 - 288
  • [7] ACID PROPERTIES OF NAH-MORDENITES - INFRARED SPECTROSCOPIC STUDIES OF AMMONIA SORPTION
    DATKA, J
    GIL, B
    KUBACKA, A
    [J]. ZEOLITES, 1995, 15 (06): : 501 - 506
  • [8] Photocatalysed degradation of two selected dyes in UV-irradiated aqueous suspensions of titania
    Faisal, M.
    Abu Tariq, M.
    Muneer, M.
    [J]. DYES AND PIGMENTS, 2007, 72 (02) : 233 - 239
  • [9] Gurr E., 1960, ENCY MICROSCOPIC STA, P367
  • [10] Hiemenz P.C., 1997, PRINCIPLES COLLOID S, P336
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