Density, Viscosity, and Refractive Index of Aqueous CO2-Loaded and -Unloaded Ethylaminoethanol (EAE) Solutions from 293.15 to 323.15 K for Post Combustion CO2 Capture

被引:20
作者
Gao, Hongxia [1 ]
Gao, Ge [1 ]
Liu, Helei [2 ]
Luo, Xiao [1 ]
Liang, Zhiwu [1 ]
Idem, Raphael O. [2 ]
机构
[1] Hunan Univ, Coll Chem & Chem Engn, Prov Hunan Key Lab Costeffect Utilizat Fossil Fue, Joint Int Ctr Capture & Storage iCCS CO2, Changsha 410082, Hunan, Peoples R China
[2] Univ Regina, CETRI, Ind & Proc Syst Engn, Regina, SK S4S 0A2, Canada
基金
加拿大创新基金会; 加拿大自然科学与工程研究理事会; 中国国家自然科学基金;
关键词
N-METHYLDIETHANOLAMINE; VOLUMETRIC PROPERTIES; MONOETHANOLAMINE; ETHANOLAMINE; DIETHANOLAMINE; SOLUBILITY; SPEED; SOUND; WATER;
D O I
10.1021/acs.jced.7b00586
中图分类号
O414.1 [热力学];
学科分类号
摘要
The physical properties of densities, viscosities, and refractive indices, which are important in kinetics and mass transfer processes were measured for aqueous CO2-loaded and-unloaded (EAE) solutions applied in CO2 absorption in the temperature range from 293.15 to 323.15 K at atmospheric pressure. Due to the limitation of the instrument and corrosive behavior with increasing concentration, the mass fractions (w(1)) of aqueous EAE solutions selected were: as 0.089, 0.178, 0.267, and 0.356, which correspond to the molar concentrations of 1, 2, 3, and 4 mol.L-1, respectively. The determined density, viscosity and refractive index data for binary EAE+H2O and ternary CO2-EAE+H2O systems were correlated using Weiland et al. model, Redlich-Kister equation, extended Arrhenius equation, and a new proposed empirical function. All the calculated density, viscosity, and refractive index data fitted well with experimental values at all operational conditions.
引用
收藏
页码:4205 / 4214
页数:10
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