A Multiferroic Perdeutero Metal-Organic Framework

被引：311
作者：
Fu, Da-Wei [1 ]
Zhang, Wen [1 ]
Cai, Hong-Ling [1 ]
Zhang, Yi [1 ]
Ge, Jia-Zhen [1 ]
Xiong, Ren-Gen [1 ]
Huang, Songping D. [1 ]
Nakamura, Takayoshi [1 ]
机构：
[1] Southeast Univ, Ordered Matter Sci Res Ctr, Nanjing 211189, Jiangsu, Peoples R China
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2011年 / 50卷 / 50期
关键词：
dielectrics; magnetic properties; organic-inorganic hybrid composites; phase transitions; PHASE-TRANSITION; FERROELECTRICITY; TEMPERATURE; COEXISTENCE; CRYSTAL;
D O I：
10.1002/anie.201103265
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Vitamin "D": The perdeutero metal-organic framework [(CD 3) 2ND 2][Co(DCOO) 3] (see structure) undergoes two phase transitions, including one above room temperature, which is unprecedented for metal formates. Magnetic and dielectric hysteresis loops make it an example of a multiferroic MOF without coupling of magnetic and electric ordering. Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码：11947 / 11951
页数：5
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