A Multiferroic Perdeutero Metal-Organic Framework

被引：315

作者：

Fu, Da-Wei ^{[1
]}

Zhang, Wen ^{[1
]}

Cai, Hong-Ling ^{[1
]}

Zhang, Yi ^{[1
]}

Ge, Jia-Zhen ^{[1
]}

Xiong, Ren-Gen ^{[1
]}

Huang, Songping D. ^{[1
]}

Nakamura, Takayoshi ^{[1
]}

机构：

[1] Southeast Univ, Ordered Matter Sci Res Ctr, Nanjing 211189, Jiangsu, Peoples R China

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2011年 / 50卷 / 50期

关键词：

dielectrics; magnetic properties; organic-inorganic hybrid composites; phase transitions; PHASE-TRANSITION; FERROELECTRICITY; TEMPERATURE; COEXISTENCE; CRYSTAL;

D O I：

10.1002/anie.201103265

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Vitamin "D": The perdeutero metal-organic framework [(CD 3) 2ND 2][Co(DCOO) 3] (see structure) undergoes two phase transitions, including one above room temperature, which is unprecedented for metal formates. Magnetic and dielectric hysteresis loops make it an example of a multiferroic MOF without coupling of magnetic and electric ordering. Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：11947 / 11951

页数：5

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