From vinyl sulfides, sulfoxides and sulfones to vinyl zirconocene derivatives

被引：53

作者：

Farhat, S ^{[1
]}

Zouev, I ^{[1
]}

Marek, I ^{[1
]}

机构：

[1] Technion Israel Inst Technol, Dept Chem, Inst Catalysis Sci & Technol, IL-32000 Haifa, Israel

来源：

TETRAHEDRON | 2004年 / 60卷 / 06期

基金：

以色列科学基金会;

关键词：

D O I：

10.1016/j.tet.2003.08.074

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

An easy and straightforward new method for the preparation of Sp(2) zirconocene derivatives from a wide range of heterosubstituted alkenes such as vinyl sulfides, sulfoxides and sulfones is described. In all cases, a complete isomerization of the stereochemistry is observed and only the E-isomer is obtained. The reactivity of the resulting vinylic organometallic can be increased by a transmetalation reaction into organocopper, organozinc or organopalladium species and, therefore, several carbon-carbon formation were easily realized. (C) 2003 Elsevier Ltd. All rights reserved.

引用

页码：1329 / 1337

页数：9

共 50 条

[31] THE CHEMISTRY OF VINYL SULFONES [J].

SIMPKINS, NS .

TETRAHEDRON, 1990, 46 (20) :6951-6984

[32] Diastereoselective halogenation of unsaturated sulfides, sulfoxides and sulfones [J].

Shainyan, BA ;

Danilevich, YS .

ZHURNAL ORGANICHESKOI KHIMII, 1998, 34 (12) :1792-1797

[33] Oxidation of Sulfides with Hydrogen Peroxide to Sulfoxides and Sulfones [J].

Sharipov, A.Kh., 1600, Maik Nauka-Interperiodica Publishing (76)

[34] Oxidation of Sulfides with Hydrogen Peroxide to Sulfoxides and Sulfones [J].

A. Kh. Sharipov .

Russian Journal of Applied Chemistry, 2003, 76 :108-113

[35] HETEROCYCLIC VINYL SULFIDES .20. REACTION OF CYCLIC SULFOXIDES WITH ACETIC ANHYDRIDE [J].

PARHAM, WE ;

BHAVSAR, MD .

JOURNAL OF ORGANIC CHEMISTRY, 1963, 28 (10) :2686-&

[36] Selective oxidation of sulfides:: selective preparation of 1-trifluoromethyl vinyl sulfoxides [J].

Ravikumar, KS ;

Barbier, F ;

Bégué, JP ;

Bonnet-Delpon, D .

JOURNAL OF FLUORINE CHEMISTRY, 1999, 95 (1-2) :123-125

[37] Oxidation of sulfides with hydrogen peroxide to sulfoxides and sulfones [J].

Sharipov, AK .

RUSSIAN JOURNAL OF APPLIED CHEMISTRY, 2003, 76 (01) :108-113

[38] CONFORMATIONAL PREFERENCES IN DIASTEREOMERIC SULFIDES, SULFOXIDES, AND SULFONES [J].

KINGSBURY, CA ;

DAY, VW ;

DAY, RO .

ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1978, 175 (MAR) :153-153

[39] Synthesis and Antimicrobial Evaluation of Sulfides, Sulfoxides, and Sulfones [J].

A. B. V. Kiran Kumar ;

K. S. V. Krishna Rao ;

M. Subhosh Chandra ;

M. C. S. Subha ;

Yong Lark Choi .

Journal of the Korean Society for Applied Biological Chemistry, 2009, 52 :34-39

[40] Synthesis and Antimicrobial Evaluation of Sulfides, Sulfoxides, and Sulfones [J].

Kumar, A. B. V. Kiran ;

Rao, K. S. V. Krishna ;

Chandra, M. Subhosh ;

Subha, M. C. S. ;

Choi, Yong Lark .

JOURNAL OF THE KOREAN SOCIETY FOR APPLIED BIOLOGICAL CHEMISTRY, 2009, 52 (01) :34-39

← 1 2 3 4 5 →